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Zorluk: KolaySolubility Calculations and Concentration Determination

Calculate the solubility in mol/dm3\text{mol/dm}^3 of sodium nitrate (NaNO3\text{NaNO}_3) at 25C25^\circ\text{C}, if 17.0 g17.0\text{ g} of the salt dissolves in 100.0 g100.0\text{ g} of water to form a saturated solution. [Relative atomic masses: Na=23,N=14,O=16\text{Na} = 23, \text{N} = 14, \text{O} = 16; density of water =1.0 g/cm3= 1.0\text{ g/cm}^3]

Cevap: 2 mol/dm^3

Cevap

The solubility of sodium nitrate at 25C25^\circ\text{C} is 2.0 mol/dm32.0\text{ mol/dm}^3.
To find solubility in mol/dm3\text{mol/dm}^3, first convert 17.0 g17.0\text{ g} of NaNO3\text{NaNO}_3 into moles by dividing by its molar mass (85.0 g/mol85.0\text{ g/mol}), obtaining 0.20 mol0.20\text{ mol}. Next, convert 100.0 g100.0\text{ g} of water into volume, which equals 0.100 dm30.100\text{ dm}^3. Dividing 0.20 mol0.20\text{ mol} by 0.100 dm30.100\text{ dm}^3 yields 2.0 mol/dm32.0\text{ mol/dm}^3.

Adım Adım Çözüm

1
Determine the molar mass of the solute (NaNO3\text{NaNO}_3)
Molar mass of NaNO3=23+14+(3×16)=85.0 g/mol\text{NaNO}_3 = 23 + 14 + (3 \times 16) = 85.0\text{ g/mol}
Molar mass is required to convert mass of solute to amount in moles.
2
Calculate the amount of NaNO3\text{NaNO}_3 in moles
Moles=17.0 g85.0 g/mol=0.20 mol\text{Moles} = \frac{17.0\text{ g}}{85.0\text{ g/mol}} = 0.20\text{ mol}
Solubility in mol/dm3\text{mol/dm}^3 measures the amount of solute in moles per cubic decimeter of solvent.
3
Convert the mass of solvent (water) to volume in dm3\text{dm}^3
100.0 g of water=100.0 cm3=0.100 dm3100.0\text{ g of water} = 100.0\text{ cm}^3 = 0.100\text{ dm}^3
Density of water is 1.0 g/cm31.0\text{ g/cm}^3, and 1000 cm3=1 dm31000\text{ cm}^3 = 1\text{ dm}^3.
4
Calculate the solubility in mol/dm3\text{mol/dm}^3
Solubility=0.20 mol0.100 dm3=2.0 mol/dm3\text{Solubility} = \frac{0.20\text{ mol}}{0.100\text{ dm}^3} = 2.0\text{ mol/dm}^3
Dividing the moles of solute by the volume of solvent in dm3\text{dm}^3 gives the concentration in mol/dm3\text{mol/dm}^3.

Anahtar Kavram

Solubility expressed in molar concentration (mol/dm³)
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