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Zorluk: KolaySolubility Calculations and Concentration Determination

A saturated solution of potassium chloride (KCl\text{KCl}) contains 14.9 g14.9\text{ g} of the salt dissolved in 100 g100\text{ g} of water at 25C25^\circ\text{C}. What is the solubility of potassium chloride in mol/dm3\text{mol/dm}^3 at this temperature?

(Take density of water = 1.0 g/cm31.0\text{ g/cm}^3, relative atomic masses: K=39\text{K} = 39, Cl=35.5\text{Cl} = 35.5)

Cevap: 2 mol/dm³

Cevap

The solubility of potassium chloride at 25C25^\circ\text{C} is 2.0 mol/dm32.0\text{ mol/dm}^3.
The correct calculated value is 2.0 mol/dm32.0\text{ mol/dm}^3. Molar mass of KCl=39+35.5=74.5 g/mol\text{KCl} = 39 + 35.5 = 74.5\text{ g/mol}. Number of moles of KCl=14.9 g74.5 g/mol=0.2 mol\text{KCl} = \frac{14.9\text{ g}}{74.5\text{ g/mol}} = 0.2\text{ mol}. Volume of water solvent =100 g=0.1 dm3= 100\text{ g} = 0.1\text{ dm}^3. Therefore, solubility =0.2 mol0.1 dm3=2.0 mol/dm3= \frac{0.2\text{ mol}}{0.1\text{ dm}^3} = 2.0\text{ mol/dm}^3.

Adım Adım Çözüm

1
Calculate the molar mass of KCl\text{KCl} and convert mass of solute to moles.
Molar mass =74.5 g/mol= 74.5\text{ g/mol}; Moles =14.9 g74.5 g/mol=0.2 mol= \frac{14.9\text{ g}}{74.5\text{ g/mol}} = 0.2\text{ mol}.
Solubility in mol/dm3\text{mol/dm}^3 requires the quantity of solute to be expressed in moles rather than grams.
2
Convert the mass/volume of solvent into decimeters cubed (dm3\text{dm}^3).
Volume =100 g=100 cm3=0.1 dm3= 100\text{ g} = 100\text{ cm}^3 = 0.1\text{ dm}^3.
Molar solubility concentration is defined per 1.0 dm31.0\text{ dm}^3 of solution/solvent.
3
Compute the concentration in mol/dm3\text{mol/dm}^3 by dividing moles of solute by volume of solvent in dm3\text{dm}^3.
Solubility =0.2 mol0.1 dm3=2.0 mol/dm3= \frac{0.2\text{ mol}}{0.1\text{ dm}^3} = 2.0\text{ mol/dm}^3.
Solubility in molarity equal to total moles divided by total volume in dm3\text{dm}^3.

Anahtar Kavram

Calculating molar solubility in mol/dm3\text{mol/dm}^3 from solute mass and solvent volume.
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