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Zorluk: OrtaCharles's Law and Absolute Temperature Scale

A sample of argon gas occupies a volume of 400 cm3400\text{ cm}^3 at a temperature of 23C-23^\circ\text{C}. If the pressure remains constant and the gas expands to a volume of 600 cm3600\text{ cm}^3, what is its final temperature in degrees Celsius (C^\circ\text{C})?

Cevap: 102 °C

Cevap

102 °C
Converting the initial temperature to Kelvin gives T1=23+273=250 KT_1 = -23 + 273 = 250\text{ K}. Applying Charles's Law V1T1=V2T2\frac{V_1}{T_1} = \frac{V_2}{T_2} gives T2=600×250400=375 KT_2 = \frac{600 \times 250}{400} = 375\text{ K}. Subtracting 273273 converts this back to degrees Celsius: 375273=102C375 - 273 = 102^\circ\text{C}.

Adım Adım Çözüm

1
Convert initial temperature from Celsius to Kelvin
T1=250 KT_1 = 250\text{ K}
Gas laws require temperature to be expressed on the absolute (Kelvin) scale.
2
Calculate final absolute temperature using Charles's Law
T2=600 cm3×250 K400 cm3=375 KT_2 = \frac{600\text{ cm}^3 \times 250\text{ K}}{400\text{ cm}^3} = 375\text{ K}
At constant pressure, volume is directly proportional to absolute temperature (V1/T1=V2/T2V_1/T_1 = V_2/T_2).
3
Convert final temperature back to degrees Celsius
t2=375273=102Ct_2 = 375 - 273 = 102^\circ\text{C}
The question explicitly requests the final answer in degrees Celsius.

Anahtar Kavram

Charles's Law states that the volume of a fixed mass of gas is directly proportional to its absolute temperature at constant pressure (VTV \propto T). Temperatures must always be converted to Kelvin (K=C+273K = ^\circ\text{C} + 273) prior to calculation.
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