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Zorluk: ZorLimiting and Excess Reactants in Chemical Reactions
Calcium carbide reacts with water according to the balanced chemical equation:
CaC2(s)+2H2O(l)Ca(OH)2(aq)+C2H2(g)\text{CaC}_{2(s)} + 2\text{H}_2\text{O}_{(l)} \rightarrow \text{Ca(OH)}_{2(aq)} + \text{C}_2\text{H}_{2(g)}
If 32.0 g32.0\text{ g} of CaC2\text{CaC}_2 is reacted with 21.6 g21.6\text{ g} of H2O\text{H}_2\text{O}, calculate the mass of the excess reactant remaining unreacted upon completion of the reaction. [Relative atomic masses: Ca=40,C=12,O=16,H=1][\text{Relative atomic masses: } \text{Ca} = 40, \text{C} = 12, \text{O} = 16, \text{H} = 1]

Cevap: 3.6 g

Cevap

3.6 g
Converting initial masses to mole values yields 0.50 mol of CaC₂ and 1.20 mol of H₂O. Based on the 1:2 mole ratio in the balanced equation, 0.50 mol of CaC₂ requires 1.00 mol of H₂O to react completely. This leaves 0.20 mol of H₂O unreacted. Converting 0.20 mol of H₂O to mass gives 0.20 mol × 18 g/mol = 3.6 g of excess reactant remaining.

Adım Adım Çözüm

1
Calculate molar masses of CaC₂ and H₂O
Molar mass of CaC₂ = 64 g/mol; Molar mass of H₂O = 18 g/mol
Molar mass is required to convert given mass values into mole quantities.
2
Convert initial masses to moles
Moles of CaC₂ = 0.50 mol; Moles of H₂O = 1.20 mol
Stoichiometric relationships depend strictly on mole ratios rather than direct mass ratios.
3
Determine limiting and excess reactants using mole ratios
CaC₂ is the limiting reactant; H₂O is in excess
According to the balanced equation coefficient ratio (1:2), 0.50 mol of CaC₂ requires 1.00 mol of H₂O. Because 1.20 mol of H₂O is present, H₂O is in excess.
4
Calculate remaining unreacted mass of excess reactant
3.6 g of excess H₂O remaining
Unreacted moles of H₂O = 1.20 - 1.00 = 0.20 mol. Mass = 0.20 mol × 18 g/mol = 3.6 g.

Anahtar Kavram

Determining limiting and excess reagents in chemical reactions and calculating unreacted leftover mass using mole ratios from balanced equations.
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