Ionic compounds are generally brittle because applying a mechanical stress causes layers of ions to shift, bringing ions of identical charge into alignment and causing strong electrostatic repulsion.
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True. Applying mechanical stress causes layers of an ionic lattice to shift, bringing like-charged ions into direct alignment; the immediate electrostatic repulsion forces the crystal planes apart, rendering ionic solids brittle.
The statement is true because mechanical stress displaces adjacent rows in an ionic lattice, shifting like-charged ions into alignment. The powerful electrostatic repulsion generated between identical charges forces the crystal layers apart, causing the ionic solid to shatter.
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Brittleness and Mechanical Cleavage of Ionic Lattice Structures