Thermal Physics

170 soru

Soru 41Soru

A heavy-duty truck tire contains a fixed mass of air at an initial absolute pressure of 2.00×105 Pa2.00 \times 10^5\text{ Pa} and a temperature of 27C27^\circ\text{C}. After traveling a long distance, friction causes the temperature of the air inside the tire to increase to 57C57^\circ\text{C} while its volume remains constant. What is the new absolute pressure of the air inside the tire in pascals (Pa\text{Pa})?

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Cevap: 220000

Cevap

The new absolute pressure of the air inside the tire is 220,000 Pa220,000\text{ Pa} (or 2.20×105 Pa2.20 \times 10^5\text{ Pa}).
According to Gay-Lussac's Law, at constant volume, pressure is directly proportional to absolute temperature (PTP \propto T). Converting temperatures to Kelvin gives T1=300 KT_1 = 300\text{ K} and T2=330 KT_2 = 330\text{ K}. Calculating P2=P1×T2T1P_2 = P_1 \times \frac{T_2}{T_1} gives 2.00×105 Pa×330300=220,000 Pa2.00 \times 10^5\text{ Pa} \times \frac{330}{300} = 220,000\text{ Pa}.

Adım Adım Çözüm

1
Convert the initial and final temperatures from Celsius to the absolute Kelvin scale.
T1=27C+273=300 KT_1 = 27^\circ\text{C} + 273 = 300\text{ K} and T2=57C+273=330 KT_2 = 57^\circ\text{C} + 273 = 330\text{ K}.
All gas law equations require absolute temperatures in Kelvin.
2
Apply the Pressure Law (Gay-Lussac's Law) for a fixed volume of gas.
P1T1=P2T2\frac{P_1}{T_1} = \frac{P_2}{T_2}
When volume is constant, gas pressure is directly proportional to absolute temperature.
3
Substitute the known values into the equation to calculate the final pressure P2P_2.
P2=2.00×105 Pa×330 K300 K=2.20×105 Pa=220,000 PaP_2 = 2.00 \times 10^5\text{ Pa} \times \frac{330\text{ K}}{300\text{ K}} = 2.20 \times 10^5\text{ Pa} = 220,000\text{ Pa}.
Multiplying the initial pressure by the ratio of absolute temperatures gives the new pressure.

Anahtar Kavram

Pressure Law (Gay-Lussac's Law)
Soru 42Soru

A flexible research balloon is filled with 1.50 m31.50\text{ m}^3 of helium gas at a temperature of 27C27^\circ\text{C}. If the gas is heated at constant pressure until its temperature reaches 127C127^\circ\text{C}, what is the new volume of the balloon?

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Cevap: 2.00 m32.00\text{ m}^3

Cevap

The new volume of the balloon is 2.00 m32.00\text{ m}^3.
The answer of 2.00 m32.00\text{ m}^3 correctly uses Charles's Law with absolute temperatures converted to Kelvin (300 K300\text{ K} and 400 K400\text{ K}), showing that heating the gas causes a proportional volume expansion.

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1
Convert temperatures from Celsius to the Kelvin absolute scale.
T1=27+273=300 KT_1 = 27 + 273 = 300\text{ K}, T2=127+273=400 KT_2 = 127 + 273 = 400\text{ K}.
Gas laws strictly require thermodynamic (absolute) temperature measured in Kelvin.
2
Apply Charles's Law for constant pressure processes.
V1T1=V2T2    V2=V1×T2T1\frac{V_1}{T_1} = \frac{V_2}{T_2} \implies V_2 = V_1 \times \frac{T_2}{T_1}.
Volume is directly proportional to absolute temperature when pressure remains constant.
3
Substitute the known values and calculate V2V_2.
V2=1.50 m3×400 K300 K=2.00 m3V_2 = 1.50\text{ m}^3 \times \frac{400\text{ K}}{300\text{ K}} = 2.00\text{ m}^3.
Simplifying the fraction 400300=43\frac{400}{300} = \frac{4}{3} gives 1.50×43=2.00 m31.50 \times \frac{4}{3} = 2.00\text{ m}^3.

Anahtar Kavram

Charles's Law (V1/T1=V2/T2V_1/T_1 = V_2/T_2 at constant pressure)
Tahmini Süre:1m 15s
Soru 43Soru

When a pure substance undergoes a change of state from liquid to vapor at its boiling point under constant atmospheric pressure, the added thermal energy increases the average kinetic energy of the molecules, causing its temperature to rise continuously until vaporization is complete.

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Cevap: False

Cevap

The statement is False. During a phase change at boiling point, thermal energy acts as latent heat, increasing the potential energy of the molecules to break intermolecular bonds while keeping average kinetic energy and temperature constant.
During boiling under constant atmospheric pressure, all absorbed thermal energy is utilized as latent heat of vaporization to do work against intermolecular forces, increasing molecular potential energy. Because temperature measures average kinetic energy, the temperature remains strictly constant until the phase change is complete.

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1
Identify the nature of heat added during a state change at constant pressure.
The added heat is latent heat of vaporization.
Heat added during a change of phase at boiling point does not produce a temperature change.
2
Relate molecular kinetic energy to temperature.
Temperature is directly proportional to the average translational kinetic energy of the molecules.
If kinetic energy increases, temperature must rise; since temperature remains constant during boiling, average kinetic energy does not change.
3
Determine the destination of the absorbed thermal energy.
Energy is stored as molecular potential energy.
The energy is spent overcoming attractive intermolecular forces to separate molecules from the liquid state into the gaseous state.

Anahtar Kavram

Constant temperature and molecular energy changes during phase transition
Soru 44Soru

A container of heat capacity 80 J K180\text{ J K}^{-1} holds 0.4 kg0.4\text{ kg} of a liquid. When 9.6 kJ9.6\text{ kJ} of heat energy is supplied to the system, the temperature of the container and liquid rises by 20 K20\text{ K}. What is the specific heat capacity of the liquid?

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Cevap: 1000 J kg1 K11000\text{ J kg}^{-1}\text{ K}^{-1}

Cevap

1000 J kg1 K11000\text{ J kg}^{-1}\text{ K}^{-1}
The option specifying 1000 J kg1 K11000\text{ J kg}^{-1}\text{ K}^{-1} is correct because out of the 9600 J9600\text{ J} supplied, 1600 J1600\text{ J} (80×2080 \times 20) is absorbed by the container. The remaining 8000 J8000\text{ J} raises the temperature of 0.4 kg0.4\text{ kg} of liquid by 20 K20\text{ K}, yielding c=80000.4×20=1000 J kg1 K1c = \frac{8000}{0.4 \times 20} = 1000\text{ J kg}^{-1}\text{ K}^{-1}.

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1
Calculate the thermal energy absorbed by the container
Qcontainer=1600 JQ_{\text{container}} = 1600\text{ J}
The heat absorbed by a body of heat capacity CC during a temperature change ΔT\Delta T is given by Qcontainer=CΔT=80 J K1×20 K=1600 JQ_{\text{container}} = C \Delta T = 80\text{ J K}^{-1} \times 20\text{ K} = 1600\text{ J}.
2
Determine the net thermal energy absorbed by the liquid
Qliquid=8000 JQ_{\text{liquid}} = 8000\text{ J}
By energy conservation, Qtotal=Qcontainer+QliquidQ_{\text{total}} = Q_{\text{container}} + Q_{\text{liquid}}, so Qliquid=9600 J1600 J=8000 JQ_{\text{liquid}} = 9600\text{ J} - 1600\text{ J} = 8000\text{ J}.
3
Calculate the specific heat capacity of the liquid
cliquid=1000 J kg1 K1c_{\text{liquid}} = 1000\text{ J kg}^{-1}\text{ K}^{-1}
Using the specific heat capacity relationship Q=mcΔTQ = m c \Delta T, cliquid=QliquidmΔT=8000 J0.4 kg×20 K=1000 J kg1 K1c_{\text{liquid}} = \frac{Q_{\text{liquid}}}{m \Delta T} = \frac{8000\text{ J}}{0.4\text{ kg} \times 20\text{ K}} = 1000\text{ J kg}^{-1}\text{ K}^{-1}.

Anahtar Kavram

Distinction and calculation involving heat capacity of a container and specific heat capacity of a substance
Soru 45Soru

The specific heat capacity of a uniform copper sphere of mass 2 kg2\text{ kg} is twice that of a uniform copper sphere of mass 1 kg1\text{ kg} at the same temperature.

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Cevap: False

Cevap

False. Specific heat capacity is an intensive property of a substance and is independent of the mass of the object.
The statement is false because specific heat capacity is an intensive property of matter. It measures the quantity of heat required to raise the temperature of 1 kg1\text{ kg} of a substance by 1 K1\text{ K} (or 1C1^\circ\text{C}). Because it is normalized per unit mass, specific heat capacity depends only on the chemical nature and state of the material, not on the total mass of the object.

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1
Distinguish between heat capacity and specific heat capacity.
Heat capacity (C=mcC = mc) is an extensive property that depends on the mass of the body, whereas specific heat capacity (c=QmΔTc = \frac{Q}{m\Delta T}) is an intensive property characteristic of the material itself.
To identify whether mass affects specific heat capacity.
2
Apply the concept of intensive properties to the two copper spheres.
Since both spheres are composed of the same material (pure copper), their specific heat capacities are identical regardless of their difference in mass.
Intensive physical properties do not change with mass or sample size.

Anahtar Kavram

Intensive vs Extensive Thermal Properties
Soru 46Soru

A solid sample of mass 0.25 kg0.25\text{ kg} at its melting point is completely melted by an electric heater rated at 700 W700\text{ W}. If the specific latent heat of fusion of the substance is 3.36×105 J kg13.36 \times 10^5\text{ J kg}^{-1}, what is the time taken to melt the sample completely at a constant temperature?

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Cevap: 120 s120\text{ s}

Cevap

The time taken to completely melt the block is 120 s120\text{ s}.
The thermal energy required to melt a substance at its melting point depends solely on its mass and specific latent heat of fusion (Q=mLfQ = m L_f). Calculating Q=0.25 kg×3.36×105 J kg1=84,000 JQ = 0.25\text{ kg} \times 3.36 \times 10^5\text{ J kg}^{-1} = 84,000\text{ J} and dividing by heater power 700 W700\text{ W} yields exactly 120 s120\text{ s}.

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1
Calculate the total thermal energy required for phase change.
Q=mLf=0.25 kg×3.36×105 J kg1=84,000 JQ = m L_f = 0.25\text{ kg} \times 3.36 \times 10^5\text{ J kg}^{-1} = 84,000\text{ J}
During a change of state at constant temperature, thermal energy is given by Q=mLfQ = m L_f.
2
Relate energy supplied by the electrical heater to time using power formula.
Q=P×t    t=QPQ = P \times t \implies t = \frac{Q}{P}
Power is the rate of energy transfer per unit time (P=QtP = \frac{Q}{t}).
3
Substitute the energy and power values to solve for time tt.
t=84,000 J700 W=120 st = \frac{84,000\text{ J}}{700\text{ W}} = 120\text{ s}
Dividing total energy required by power gives time in seconds.

Anahtar Kavram

Latent Heat of Fusion and Electrical Thermal Energy
Soru 47Soru

A solid metal block absorbs 3600 J3600\text{ J} of thermal energy when its temperature increases from 20C20^\circ\text{C} to 60C60^\circ\text{C}. If the block has a mass of 2.0 kg2.0\text{ kg}, what is the heat capacity of the block?

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Cevap: 90 J K190\text{ J K}^{-1}

Cevap

The heat capacity of the block is 90 J K190\text{ J K}^{-1}.
The correct answer is 90 J K190\text{ J K}^{-1} because heat capacity is defined as C=QΔTC = \frac{Q}{\Delta T}. Dividing the absorbed heat of 3600 J3600\text{ J} by the temperature change of 40 K40\text{ K} yields 90 J K190\text{ J K}^{-1}.

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1
Calculate the temperature change (ΔT\Delta T)
ΔT=60C20C=40 K\Delta T = 60^\circ\text{C} - 20^\circ\text{C} = 40\text{ K}
Heat capacity depends on the change in temperature, not the initial or final temperature values.
2
Apply the formula for total heat capacity (C=QΔTC = \frac{Q}{\Delta T})
C=3600 J40 K=90 J K1C = \frac{3600\text{ J}}{40\text{ K}} = 90\text{ J K}^{-1}
Heat capacity CC measures the total thermal energy required to raise the entire body's temperature by one degree Kelvin (or Celsius).

Anahtar Kavram

Heat capacity (CC) represents the heat quantity needed to change a body's temperature by 1 K1\text{ K} (C=QΔTC = \frac{Q}{\Delta T}), whereas specific heat capacity (cc) is heat capacity per unit mass (c=QmΔTc = \frac{Q}{m\Delta T}).
Tahmini Süre:1m 0s
Soru 48Soru

An electric heater rated at 100 W100\text{ W} is used to heat a metal block of mass 2.5 kg2.5\text{ kg} for 5 minutes5\text{ minutes}. If the temperature of the block increases from 25C25^\circ\text{C} to 45C45^\circ\text{C} and no heat energy is lost to the surroundings, what is the specific heat capacity of the metal?

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Cevap: 600

Cevap

600 J kg1 K1600\text{ J kg}^{-1}\text{ K}^{-1}
The energy transferred by the 100 W100\text{ W} heater over 300 seconds300\text{ seconds} is Q=30,000 JQ = 30,000\text{ J}. Dividing this by the product of mass (2.5 kg2.5\text{ kg}) and temperature rise (20 K20\text{ K}) yields the specific heat capacity c=600 J kg1 K1c = 600\text{ J kg}^{-1}\text{ K}^{-1}.

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1
Calculate total electrical heat energy supplied to the metal block
Q=P×t=100 W×(5×60 s)=30,000 JQ = P \times t = 100\text{ W} \times (5 \times 60\text{ s}) = 30,000\text{ J}
Heat energy supplied by an electric heater is given by power multiplied by heating time in seconds.
2
Calculate the change in temperature
ΔT=45C25C=20 K\Delta T = 45^\circ\text{C} - 25^\circ\text{C} = 20\text{ K}
Temperature difference is calculated by subtracting initial temperature from final temperature.
3
Solve for the specific heat capacity
c=QmΔT=30,000 J2.5 kg×20 K=600 J kg1 K1c = \frac{Q}{m \Delta T} = \frac{30,000\text{ J}}{2.5\text{ kg} \times 20\text{ K}} = 600\text{ J kg}^{-1}\text{ K}^{-1}
Specific heat capacity is the amount of heat energy required to raise the temperature of unit mass by one kelvin.

Anahtar Kavram

Specific Heat Capacity and Electrical Energy
Soru 49Soru

A solid substance of mass 0.50 kg0.50\text{ kg} at its melting point is supplied with thermal energy by an electric heater operating at a constant rate of 150 W150\text{ W}. If it takes 4.0 minutes4.0\text{ minutes} for the solid to melt completely without any change in temperature, what is the specific latent heat of fusion of the substance?

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Cevap: 7.2×104 J kg17.2 \times 10^4\text{ J kg}^{-1}

Cevap

The specific latent heat of fusion of the substance is 7.2×104 J kg17.2 \times 10^4\text{ J kg}^{-1}.
During a change of phase at constant temperature, the thermal energy supplied is used exclusively to weaken intermolecular bonds without increasing kinetic energy or temperature. The heat supplied is Q=P×t=150 W×240 s=36000 JQ = P \times t = 150\text{ W} \times 240\text{ s} = 36\,000\text{ J}. Using Q=mLQ = mL, the specific latent heat L=Qm=36000 J0.50 kg=7.2×104 J kg1L = \frac{Q}{m} = \frac{36\,000\text{ J}}{0.50\text{ kg}} = 7.2 \times 10^4\text{ J kg}^{-1}.

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1
Convert the given heating duration into SI units (seconds).
t=4.0 minutes=4.0×60 s=240 st = 4.0\text{ minutes} = 4.0 \times 60\text{ s} = 240\text{ s}.
Standard calculation of thermal energy requires time to be in seconds when power is given in Watts.
2
Calculate the total thermal energy supplied by the heater.
Q=P×t=150 W×240 s=36000 J=3.6×104 JQ = P \times t = 150\text{ W} \times 240\text{ s} = 36\,000\text{ J} = 3.6 \times 10^4\text{ J}.
Electrical energy supplied is completely converted into heat energy.
3
Apply the latent heat formula to find the specific latent heat of fusion.
L=Qm=36000 J0.50 kg=72000 J kg1=7.2×104 J kg1L = \frac{Q}{m} = \frac{36\,000\text{ J}}{0.50\text{ kg}} = 72\,000\text{ J kg}^{-1} = 7.2 \times 10^4\text{ J kg}^{-1}.
During a change of state at constant temperature, heat absorbed is given by Q=mLQ = mL.

Anahtar Kavram

Latent Heat of Fusion
Tahmini Süre:1m 30s
Soru 50Soru

At a weather recording station, the air temperature is 25C25^\circ\text{C} and the relative humidity is recorded as 60%60\%. If the saturated vapour pressure of water at 25C25^\circ\text{C} is 24.0 mmHg24.0\text{ mmHg}, what is the actual partial vapour pressure of water present in the atmosphere?

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Cevap: 14.4 mmHg14.4\text{ mmHg}

Cevap

The actual partial vapour pressure of water present in the atmosphere is 14.4 mmHg14.4\text{ mmHg}.
Relative humidity is defined as the ratio of actual partial vapour pressure to saturated vapour pressure at the same temperature, expressed as a percentage. Therefore, the actual partial vapour pressure is 60%60\% of 24.0 mmHg24.0\text{ mmHg}, which equals 14.4 mmHg14.4\text{ mmHg}.

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1
State the standard relationship defining relative humidity in terms of vapour pressures.
Relative Humidity (R.H.)=Partial Vapour PressureSaturated Vapour Pressure at Air Temp×100%\text{Relative Humidity (R.H.)} = \frac{\text{Partial Vapour Pressure}}{\text{Saturated Vapour Pressure at Air Temp}} \times 100\%
Relative humidity quantifies how close the air is to maximum moisture saturation at a given temperature.
2
Substitute the given numerical values into the relative humidity formula.
60%=P24.0 mmHg×100%60\% = \frac{P}{24.0\text{ mmHg}} \times 100\%
Here PP represents the unknown actual partial vapour pressure of water in the atmosphere.
3
Rearrange the equation to isolate and solve for PP.
P=0.60×24.0 mmHg=14.4 mmHgP = 0.60 \times 24.0\text{ mmHg} = 14.4\text{ mmHg}
Multiplying the saturated vapour pressure by 0.600.60 yields the actual partial vapour pressure.

Anahtar Kavram

Relative Humidity and Vapour Pressure Calculation
Soru 51Soru

A glass window pane has an area of 1.50 m21.50\text{ m}^2 and a thickness of 4.0 mm4.0\text{ mm}. The inner and outer surface temperatures of the glass are maintained at 25C25^\circ\text{C} and 5C5^\circ\text{C} respectively. If the thermal conductivity of glass is 0.80 Wm1K10.80\text{ W}\cdot\text{m}^{-1}\cdot\text{K}^{-1}, what is the rate of heat transfer through the glass pane by conduction?

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Cevap: 6000 W6000\text{ W}

Cevap

The rate of heat transfer through the glass pane is 6000 W6000\text{ W}.
According to Fourier's law of thermal conduction, the rate of heat flow Qt\frac{Q}{t} is given by Qt=kA(T1T2)d\frac{Q}{t} = \frac{k A (T_1 - T_2)}{d}. Substituting k=0.80 Wm1K1k = 0.80\text{ W}\cdot\text{m}^{-1}\cdot\text{K}^{-1}, A=1.50 m2A = 1.50\text{ m}^2, T1T2=20 KT_1 - T_2 = 20\text{ K}, and d=0.004 md = 0.004\text{ m} gives Qt=0.80×1.50×200.004=6000 W\frac{Q}{t} = \frac{0.80 \times 1.50 \times 20}{0.004} = 6000\text{ W}.

Adım Adım Çözüm

1
Identify the given values and convert all quantities to SI units.
Area A=1.50 m2A = 1.50\text{ m}^2, thermal conductivity k=0.80 Wm1K1k = 0.80\text{ W}\cdot\text{m}^{-1}\cdot\text{K}^{-1}, thickness d=4.0 mm=4.0×103 md = 4.0\text{ mm} = 4.0 \times 10^{-3}\text{ m}, and temperature difference ΔT=25C5C=20 K\Delta T = 25^\circ\text{C} - 5^\circ\text{C} = 20\text{ K}.
Fourier's law requires all linear dimensions to be in meters and temperatures in kelvins/degrees Celsius consistently.
2
Apply Fourier's law of thermal conduction equation.
Qt=kAΔTd\frac{Q}{t} = \frac{k A \Delta T}{d}
The rate of heat conduction is directly proportional to thermal conductivity, surface area, and temperature difference, and inversely proportional to material thickness.
3
Substitute the values into the formula and solve.
Qt=0.80×1.50×204.0×103=240.004=6000 W\frac{Q}{t} = \frac{0.80 \times 1.50 \times 20}{4.0 \times 10^{-3}} = \frac{24}{0.004} = 6000\text{ W}
Calculates the total heat energy conducted per second across the window pane.

Anahtar Kavram

Thermal Conduction Rate Equation
Tahmini Süre:1m 30s
Soru 52Soru

A thermometer is calibrated on a custom scale, XX, where the ice point (0C0^\circ\text{C}) is marked as 10X-10^\circ\text{X} and the steam point (100C100^\circ\text{C}) is marked as 110X110^\circ\text{X}. What is the reading on this custom scale when a standard Celsius thermometer reads 35C35^\circ\text{C}?

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Cevap: 32

Cevap

32 °X
Using the linear temperature interpolation formula XLFPXUFPXLFPX=CLFPCUFPCLFPC\frac{X - \text{LFP}_X}{\text{UFP}_X - \text{LFP}_X} = \frac{C - \text{LFP}_C}{\text{UFP}_C - \text{LFP}_C}, substituting LFPX=10\text{LFP}_X = -10, UFPX=110\text{UFP}_X = 110, C=35C = 35, LFPC=0\text{LFP}_C = 0, and UFPC=100\text{UFP}_C = 100 gives X(10)110(10)=3501000\frac{X - (-10)}{110 - (-10)} = \frac{35 - 0}{100 - 0}. Simplifying gives X+10120=0.35\frac{X + 10}{120} = 0.35, leading to X+10=42X + 10 = 42, so X=32XX = 32^\circ\text{X}.

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1
Determine fundamental intervals for both temperature scales
Celsius fundamental interval = 1000=100C100 - 0 = 100^\circ\text{C}; Custom scale fundamental interval = 110(10)=120X110 - (-10) = 120^\circ\text{X}
Linear temperature scale interpolation requires calculating the total interval between the lower fixed point (LFP) and upper fixed point (UFP).
2
Set up the ratio equation between the two thermometric scales
X(10)120=350100\frac{X - (-10)}{120} = \frac{35 - 0}{100}
The fractional position of any given temperature relative to its fixed points must be equal on all linear scales.
3
Solve the algebraic equation for XX
X+10=120×0.35=42    X=32XX + 10 = 120 \times 0.35 = 42 \implies X = 32^\circ\text{X}
Isolating XX gives the corresponding reading on the custom temperature scale.

Anahtar Kavram

Linear Temperature Scale Conversion and Interpolation
Soru 53Soru

At a constant temperature, doubling the volume of a sealed container holding a liquid and its saturated vapour will cause the saturated vapour pressure to be halved.

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Cevap: False

Cevap

The statement is false. Saturated vapour pressure depends exclusively on temperature and is independent of the container volume.
Saturated vapour pressure is entirely independent of the volume of the space occupied by the vapour. As long as liquid remains in the container to evaporate, expanding the volume simply causes more liquid to evaporate until the vapour pressure reaches its equilibrium saturation value at that temperature.

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1
Analyze the physical state of a saturated vapour in contact with its liquid.
A saturated vapour exists in dynamic equilibrium with its liquid phase, meaning the rate of evaporation equals the rate of condensation at that specific temperature.
Dynamic equilibrium determines the equilibrium vapour pressure above a liquid surface.
2
Examine the effect of increasing the container volume at constant temperature.
Expanding the volume temporarily reduces vapour concentration, causing the rate of evaporation to exceed condensation until the space is re-saturated.
Phase change allows the mass of the gas phase to change, unlike in closed ideal gas systems.
3
Conclude the value of the final vapour pressure.
The pressure returns to the exact same saturated vapour pressure (SVP) value as before the expansion.
SVP is an intrinsic property dependent only on temperature and the identity of the liquid, independent of volume.

Anahtar Kavram

Independence of Saturated Vapour Pressure from Volume
Soru 54Soru

A closed vessel initially contains air saturated with water vapour at 27C27^\circ\text{C} under a total pressure of 1.04×105 Pa1.04 \times 10^5\text{ Pa}. Given that the saturated vapour pressure of water at 27C27^\circ\text{C} is 0.04×105 Pa0.04 \times 10^5\text{ Pa}, what is the final total pressure inside the vessel if its volume is compressed to half of its initial volume while maintaining the temperature at 27C27^\circ\text{C}?

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Cevap: 2.04×105 Pa2.04 \times 10^5\text{ Pa}

Cevap

The final total pressure inside the vessel is 2.04×105 Pa2.04 \times 10^5\text{ Pa}.
The total pressure is the sum of the partial pressures of dry air and saturated water vapour. Under isothermal compression to half volume, dry air follows Boyle's law and its partial pressure doubles from 1.00×105 Pa1.00 \times 10^5\text{ Pa} to 2.00×105 Pa2.00 \times 10^5\text{ Pa}. The saturated water vapour pressure remains constant at 0.04×105 Pa0.04 \times 10^5\text{ Pa} because liquid condenses out. Summing these yields 2.04×105 Pa2.04 \times 10^5\text{ Pa}.

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1
Calculate the initial partial pressure of the dry air.
Pair, 1=Ptotal, 1Pvapour, 1=1.04×105 Pa0.04×105 Pa=1.00×105 PaP_{\text{air, 1}} = P_{\text{total, 1}} - P_{\text{vapour, 1}} = 1.04 \times 10^5\text{ Pa} - 0.04 \times 10^5\text{ Pa} = 1.00 \times 10^5\text{ Pa}.
According to Dalton's law of partial pressures, the total pressure of a gas mixture is the sum of the partial pressures of its individual components.
2
Determine the final partial pressure of dry air after isothermal compression.
Pair, 2=Pair, 1×V1V2=1.00×105 Pa×2=2.00×105 PaP_{\text{air, 2}} = P_{\text{air, 1}} \times \frac{V_1}{V_2} = 1.00 \times 10^5\text{ Pa} \times 2 = 2.00 \times 10^5\text{ Pa}.
Dry air behaves as an ideal gas and follows Boyle's law (P1V1=P2V2P_1 V_1 = P_2 V_2) at constant temperature.
3
Determine the final partial pressure of the saturated water vapour.
Pvapour, 2=0.04×105 PaP_{\text{vapour, 2}} = 0.04 \times 10^5\text{ Pa}.
Saturated vapour pressure depends strictly on temperature. When compressed at constant temperature, excess vapour condenses into liquid, keeping the partial pressure constant at the saturated value.
4
Sum the final partial pressures to find the new total pressure.
Ptotal, 2=Pair, 2+Pvapour, 2=2.00×105 Pa+0.04×105 Pa=2.04×105 PaP_{\text{total, 2}} = P_{\text{air, 2}} + P_{\text{vapour, 2}} = 2.00 \times 10^5\text{ Pa} + 0.04 \times 10^5\text{ Pa} = 2.04 \times 10^5\text{ Pa}.
The total final pressure is the sum of the new dry air pressure and the unchanged saturated vapour pressure.

Anahtar Kavram

Saturated Vapour Pressure and Gas Law Applications
Tahmini Süre:2m 0s
Soru 55Soru

Match each kinetic theory concept on the left with its correct physical description on the right.

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Öğeler

Temperature of a gas
Pressure of a gas
Root-mean-square speed

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Cevap

Temperature matches with the measure of average translational kinetic energy; Pressure matches with the average force per unit area exerted by colliding gas molecules on container walls; Root-mean-square speed matches with the square root of the mean of squared speeds.
Temperature measures average translational kinetic energy per particle. Pressure originates from force per unit area due to elastic wall collisions. Root-mean-square speed is the square root of the mean of squared molecular speeds.

Adım Adım Çözüm

1
Identify the kinetic theory definition of Temperature
Temperature is directly proportional to the mean translational kinetic energy of the gas particles (EkTE_k \propto T).
Absolute temperature reflects the average kinetic energy of molecular motion.
2
Identify the microscopic origin of Gas Pressure
Pressure is caused by molecular collisions with the container walls, transferring momentum and creating force per unit area.
Frequent elastic collisions of particles on container walls produce measurable pressure.
3
Identify the mathematical definition of Root-Mean-Square Speed
vrms=v2v_{rms} = \sqrt{\overline{v^2}}, representing the square root of the average of squared molecular velocities.
This parameter represents the effective speed of gas particles relevant to thermal kinetic energy.

Anahtar Kavram

Kinetic Theory Interpretation of Gas Properties
Soru 56Soru

The saturated vapour pressure of water at the dew point of a mass of air is 12 mmHg12\text{ mmHg}, while the saturated vapour pressure at the actual air temperature is 24 mmHg24\text{ mmHg}. Calculate the relative humidity of the air.

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Cevap: 50

Cevap

The relative humidity of the air is 50%.
Relative humidity is the ratio of the saturated vapour pressure at the dew point to the saturated vapour pressure at the actual air temperature, expressed as a percentage: (12 mmHg / 24 mmHg) * 100% = 50%.

Adım Adım Çözüm

1
Identify the saturated vapour pressure at the dew point and at the air temperature.
SVP at dew point = 12 mmHg; SVP at air temperature = 24 mmHg.
Relative humidity relies on the ratio of partial vapour pressure (SVP at dew point) to maximum vapour pressure at air temperature.
2
Apply the relative humidity formula.
Relative Humidity = (SVP at dew point / SVP at air temperature) * 100%
This formula defines the percentage saturation of the air.
3
Substitute the values and evaluate.
(12 / 24) * 100% = 50%
Dividing 12 by 24 gives 0.5, which equals 50% when multiplied by 100.

Anahtar Kavram

Relative Humidity Calculation
Tahmini Süre:45s
Soru 57Soru

A constant-volume gas thermometer registers a pressure of 50kPa50\,\text{kPa} at the ice point (0C0^\circ\text{C}) and 70kPa70\,\text{kPa} at the steam point (100C100^\circ\text{C}). What is the temperature when the gas pressure measured by the thermometer is 62kPa62\,\text{kPa}?

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Cevap: 60C60^\circ\text{C}

Cevap

60C60^\circ\text{C}
The temperature θ\theta on the Celsius scale is given by the ratio of the change in thermometric property from the ice point to the total fundamental interval, scaled by 100. Substituting P0=50kPaP_0 = 50\,\text{kPa}, P100=70kPaP_{100} = 70\,\text{kPa}, and Pθ=62kPaP_\theta = 62\,\text{kPa} gives θ=62507050×100=1220×100=60C\theta = \frac{62 - 50}{70 - 50} \times 100 = \frac{12}{20} \times 100 = 60^\circ\text{C}.

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1
Identify the given thermometric property values at the fixed points and target state
P0=50kPaP_0 = 50\,\text{kPa}, P100=70kPaP_{100} = 70\,\text{kPa}, and Pθ=62kPaP_\theta = 62\,\text{kPa}
These represent the lower fixed point, upper fixed point, and unknown temperature reading respectively.
2
Apply the general thermometric scale conversion formula
θ=PθP0P100P0×100C\theta = \frac{P_\theta - P_0}{P_{100} - P_0} \times 100^\circ\text{C}
Temperature on the Celsius scale varies linearly with the thermometric property relative to fixed points.
3
Substitute the values into the formula and solve for θ\theta
θ=62507050×100=1220×100=60C\theta = \frac{62 - 50}{70 - 50} \times 100 = \frac{12}{20} \times 100 = 60^\circ\text{C}
Carrying out the arithmetic yields the exact temperature of 60C60^\circ\text{C}.

Anahtar Kavram

Linear interpolation on temperature scales using thermometric properties
Tahmini Süre:1m 0s
Soru 58Soru

A thermometric property XX of a system has a value of 15.0units15.0\,\text{units} at the ice point (0C0^\circ\text{C}) and 75.0units75.0\,\text{units} at the steam point (100C100^\circ\text{C}). If the thermometric property is measured as 33.0units33.0\,\text{units} when immersed in a chemical bath, what is the temperature of the bath on the absolute thermodynamic scale?

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Cevap: 303K303\,\text{K}

Cevap

303K303\,\text{K}
The temperature of the bath on the Celsius scale is found by taking the ratio of the change in thermometric property from the ice point to the total fundamental interval: 33.015.075.015.0×100C=1860×100=30C\frac{33.0 - 15.0}{75.0 - 15.0} \times 100^\circ\text{C} = \frac{18}{60} \times 100 = 30^\circ\text{C}. Converting this temperature to the absolute (Kelvin) scale requires adding 273K273\,\text{K}, yielding 30+273=303K30 + 273 = 303\,\text{K}.

Adım Adım Çözüm

1
Identify the given thermometric values for the fixed points and the unknown state
X0=15.0unitsX_0 = 15.0\,\text{units} (ice point, 0C0^\circ\text{C}), X100=75.0unitsX_{100} = 75.0\,\text{units} (steam point, 100C100^\circ\text{C}), and XT=33.0unitsX_T = 33.0\,\text{units}
Linear thermometric interpolation requires defining the fixed reference points and the measured property value.
2
Calculate the temperature on the Celsius scale using the linear scale formula
θ=XTX0X100X0×100C=33.015.075.015.0×100=18.060.0×100=30C\theta = \frac{X_T - X_0}{X_{100} - X_0} \times 100^\circ\text{C} = \frac{33.0 - 15.0}{75.0 - 15.0} \times 100 = \frac{18.0}{60.0} \times 100 = 30^\circ\text{C}
The temperature change relative to the fundamental interval determines the position on the Celsius scale.
3
Convert the temperature from degrees Celsius to Kelvin
T=θ+273=30+273=303KT = \theta + 273 = 30 + 273 = 303\,\text{K}
The absolute thermodynamic scale (Kelvin) is shifted from the Celsius scale by adding 273K273\,\text{K}.

Anahtar Kavram

Linear interpolation of temperature using thermometric properties and conversion to the absolute scale
Tahmini Süre:2m 0s
Soru 59Soru

Match each type of thermometer with its corresponding physical thermometric property.

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Öğeler

Liquid-in-glass thermometer
Constant-volume gas thermometer
Resistance thermometer
Thermocouple

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Cevap

Liquid-in-glass thermometer matches change in length or volume of a liquid column; Constant-volume gas thermometer matches change in pressure of a gas; Resistance thermometer matches change in electrical resistance; Thermocouple matches electromotive force (e.m.f.) produced across junctions.
Each thermometer is accurately matched to the physical property that undergoes a measurable change as temperature varies.

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1
Identify the defining physical property that varies with temperature for each instrument.
Each thermometer operates on a distinct physical property that changes predictably when heated or cooled.
Thermometric properties must be reproducible and continuously measurable across a temperature range.
2
Pair each instrument with its specific thermometric property.
Liquid-in-glass pairs with liquid column expansion/length; constant-volume gas thermometer pairs with gas pressure; resistance thermometer pairs with electrical resistance; thermocouple pairs with thermoelectric e.m.f.
These pairs represent standard physical principles used in thermometry.

Anahtar Kavram

Thermometric properties and operating principles of thermometers
Soru 60Soru

Match each temperature scale reference state on the left with its correct thermodynamic definition on the right.

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Öğeler

Absolute zero (0 K0\text{ K})
Ice point (0C0^\circ\text{C})
Steam point (100C100^\circ\text{C})
Triple point of water (273.16 K273.16\text{ K})

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Cevap

Absolute zero matches with the state of minimum molecular kinetic energy. The ice point matches with the lower fixed point of pure melting ice at standard pressure. The steam point matches with the upper fixed point of pure boiling water steam at standard pressure. The triple point of water matches with the thermodynamic equilibrium state of ice, liquid water, and water vapour.
Each temperature scale reference point is correctly paired with its defining physical state: absolute zero represents minimum molecular kinetic energy, the ice point represents melting ice at standard pressure, the steam point represents steam from boiling water at standard pressure, and the triple point represents the three-phase equilibrium of water.

Adım Adım Çözüm

1
Identify the definition of absolute zero.
Absolute zero (0 K0\text{ K}) corresponds to the state of minimum internal molecular kinetic energy.
At 0 K0\text{ K}, thermal motion of particles theoretically ceases.
2
Identify the definition of the ice point.
The ice point (0C0^\circ\text{C}) corresponds to pure melting ice at standard atmospheric pressure.
It serves as the standard lower fixed point on the Celsius temperature scale.
3
Identify the definition of the steam point.
The steam point (100C100^\circ\text{C}) corresponds to steam from pure boiling water at standard atmospheric pressure.
It serves as the standard upper fixed point on the Celsius temperature scale.
4
Identify the definition of the triple point of water.
The triple point (273.16 K273.16\text{ K}) is the unique thermodynamic state where ice, liquid water, and steam coexist in equilibrium.
It is used as a single fundamental reference point on the Kelvin thermodynamic scale.

Anahtar Kavram

Temperature Scale Fixed Points and Reference States
Tahmini Süre:1m 30s
ÖncekiSayfa 3 / 9Sonraki