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Question 7161Question

A laboratory mixture contains insoluble chalk powder (calcium carbonate) suspended in water. Which physical separation technique is most appropriate for collecting the chalk as a residue and the clear water as a filtrate?

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Answer: Filtration

Answer

Filtration
Filtration is the standard method for separating an insoluble solid from a liquid. The filter paper acts as a mechanical sieve; insoluble chalk particles remain on top as the residue, while pure liquid water passes through as the filtrate.

Step-by-Step Solution

1
Identify the physical state and solubility of the components in the mixture.
Chalk (calcium carbonate) is an insoluble solid suspended in liquid water.
Choosing the correct separation technique depends on whether the solute is soluble or insoluble in the solvent.
2
Select the separation technique designed for insoluble solid-liquid mixtures.
Filtration is selected because the filter paper pores trap the insoluble chalk particles (residue) while letting water molecules pass through (filtrate).
Techniques like evaporation or distillation are intended for soluble solutes or miscible liquids, whereas filtration directly separates suspended particles.

Key Concept

Separation of insoluble solids from liquids using filtration
Estimated Time:45s
Question 7162Question

A sample of nitrogen gas enclosed in a constant-volume container exerts a pressure of 2.50 atm2.50\text{ atm} at a temperature of 23C-23^\circ\text{C}. To what temperature, in degrees Celsius (C^\circ\text{C}), must the gas be heated so that its pressure increases to 4.00 atm4.00\text{ atm}?

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Answer: 127

Answer

The gas must be heated to 127C127^\circ\text{C}.
According to Gay-Lussac's Pressure Law, for a fixed mass of gas at constant volume, pressure is directly proportional to absolute temperature (PTP \propto T). Converting 23C-23^\circ\text{C} to Kelvin gives 250 K250\text{ K}. Solving 2.50250=4.00T2\frac{2.50}{250} = \frac{4.00}{T_2} gives T2=400 KT_2 = 400\text{ K}. Converting back to Celsius (400273400 - 273) yields the correct temperature of 127C127^\circ\text{C}.

Step-by-Step Solution

1
Convert the initial temperature from Celsius to the thermodynamic temperature scale (Kelvin).
T1=23+273=250 KT_1 = -23 + 273 = 250\text{ K}
Gas laws strictly require temperature to be expressed in Kelvin.
2
Use Gay-Lussac's Pressure Law equation P1T1=P2T2\frac{P_1}{T_1} = \frac{P_2}{T_2} to solve for T2T_2.
T2=P2×T1P1=4.00×2502.50=400 KT_2 = \frac{P_2 \times T_1}{P_1} = \frac{4.00 \times 250}{2.50} = 400\text{ K}
At constant volume, the pressure of a given mass of gas is directly proportional to its absolute temperature.
3
Convert the calculated temperature T2T_2 back to degrees Celsius.
t2=400273=127Ct_2 = 400 - 273 = 127^\circ\text{C}
The question explicitly requests the final temperature in degrees Celsius.

Key Concept

Pressure Law (Gay-Lussac's Law)
Question 7163Question

An uncatalyzed exothermic reaction has an activation energy for the forward reaction of 110 kJ mol1110\text{ kJ mol}^{-1} and an overall enthalpy change (ΔH\Delta H) of 70 kJ mol1-70\text{ kJ mol}^{-1}. If a catalyst is added that lowers the activation energy of the forward reaction by 35 kJ mol135\text{ kJ mol}^{-1}, what is the activation energy of the reverse catalyzed reaction?

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Answer: 145 kJ mol1145\text{ kJ mol}^{-1}

Answer

145 kJ mol1145\text{ kJ mol}^{-1}
For an exothermic reaction, the reverse activation energy is greater than the forward activation energy by ΔH|\Delta H|. The uncatalyzed reverse activation energy is 110(70)=180 kJ mol1110 - (-70) = 180\text{ kJ mol}^{-1}. Since a catalyst reduces both forward and reverse activation energy barriers by the exact same amount (35 kJ mol135\text{ kJ mol}^{-1}), the reverse catalyzed activation energy is 18035=145 kJ mol1180 - 35 = 145\text{ kJ mol}^{-1}. Alternatively, using the catalyzed forward barrier of 75 kJ mol175\text{ kJ mol}^{-1}, Ea,rev, cat=75(70)=145 kJ mol1E_{a,\text{rev, cat}} = 75 - (-70) = 145\text{ kJ mol}^{-1}.

Step-by-Step Solution

1
Calculate the activation energy for the forward catalyzed reaction.
Ea,fwd, cat=110 kJ mol135 kJ mol1=75 kJ mol1E_{a,\text{fwd, cat}} = 110\text{ kJ mol}^{-1} - 35\text{ kJ mol}^{-1} = 75\text{ kJ mol}^{-1}
A catalyst lowers the energy barrier for the forward reaction by the specified amount.
2
Relate the forward activation energy, reverse activation energy, and enthalpy change.
ΔH=Ea,fwd, catEa,rev, cat\Delta H = E_{a,\text{fwd, cat}} - E_{a,\text{rev, cat}}
The difference between forward and reverse activation energy yields the reaction enthalpy change.
3
Solve for the reverse catalyzed activation energy.
Ea,rev, cat=75 kJ mol1(70 kJ mol1)=145 kJ mol1E_{a,\text{rev, cat}} = 75\text{ kJ mol}^{-1} - (-70\text{ kJ mol}^{-1}) = 145\text{ kJ mol}^{-1}
Subtracting a negative enthalpy change adds its absolute value to the forward activation energy.

Key Concept

Effect of Catalysts on Forward and Reverse Activation Energies in Energy Profile Diagrams
Estimated Time:1m 30s
Question 7164Question

The speed vv of a longitudinal wave propagating through a gas depends on the pressure PP of the gas and its density ρ\rho according to the dimensional relationship v=CPxρyv = C P^x \rho^y, where CC is a dimensionless constant. Using dimensional analysis, what is the numerical value of xyx - y?

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Answer: 1

Answer

The numerical value of xyx - y is 1.0.
By applying the principle of dimensional homogeneity, the exponents are determined as x=0.5x = 0.5 (for pressure) and y=0.5y = -0.5 (for density). Thus, xy=0.5(0.5)=1.0x - y = 0.5 - (-0.5) = 1.0.

Step-by-Step Solution

1
Determine the dimensions of speed, pressure, and density.
[v]=[LT1][v] = [L T^{-1}], [P]=[ML1T2][P] = [M L^{-1} T^{-2}], and [ρ]=[ML3][\rho] = [M L^{-3}].
Dimensional homogeneity requires expressed physical quantities to be broken down into fundamental dimensions (MM, LL, TT).
2
Substitute dimensions into the relationship v=CPxρyv = C P^x \rho^y.
[LT1]=[ML1T2]x[ML3]y=Mx+yLx3yT2x[L T^{-1}] = [M L^{-1} T^{-2}]^x \, [M L^{-3}]^y = M^{x+y} \, L^{-x-3y} \, T^{-2x}.
This establishes a system of algebraic equations by equating exponents of corresponding fundamental dimensions.
3
Solve for exponents xx and yy.
From time TT: 2x=1    x=0.5-2x = -1 \implies x = 0.5. From mass MM: x+y=0    y=0.5x + y = 0 \implies y = -0.5.
Equating the powers of fundamental dimensions on both sides yields the values of xx and yy.
4
Calculate the required expression (xy)(x - y).
xy=0.5(0.5)=1.0x - y = 0.5 - (-0.5) = 1.0.
Subtracting negative 0.50.5 from 0.50.5 results in 1.01.0.

Key Concept

Dimensional Analysis and Homogeneity
Question 7165Question

A naturally occurring sample of boron consists of two stable isotopes, 10B^{10}\text{B} and 11B^{11}\text{B}. If the relative percentage abundance of 10B^{10}\text{B} is 20.0%20.0\% and that of 11B^{11}\text{B} is 80.0%80.0\%, what is the relative atomic mass of boron?

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Answer: 10.8

Answer

The relative atomic mass of boron is 10.810.8.
The relative atomic mass of an element is defined as the weighted average mass of its naturally occurring isotopes relative to 112th\frac{1}{12}\text{th} the mass of a carbon-12 atom. Applying the formula RAM=(isotopic mass×% abundance)100\text{RAM} = \frac{\sum (\text{isotopic mass} \times \% \text{ abundance})}{100}, we get (10×20)+(11×80)100=200+880100=10.8\frac{(10 \times 20) + (11 \times 80)}{100} = \frac{200 + 880}{100} = 10.8.

Step-by-Step Solution

1
Determine the mass contribution of the 10B^{10}\text{B} isotope
10×0.20=2.010 \times 0.20 = 2.0
The weighted contribution of an isotope is its mass multiplied by its fractional abundance.
2
Determine the mass contribution of the 11B^{11}\text{B} isotope
11×0.80=8.811 \times 0.80 = 8.8
The weighted contribution of the second isotope is calculated using its percentage abundance.
3
Sum the weighted contributions to find the relative atomic mass
2.0+8.8=10.82.0 + 8.8 = 10.8
The relative atomic mass of an element is the weighted average mass of all naturally occurring isotopes relative to carbon-12.

Key Concept

Calculation of Relative Atomic Mass from Isotopic Abundances
Question 7166Question

Two sound waves of frequencies 440 Hz440\text{ Hz} and 445 Hz445\text{ Hz} travel through air and superpose to produce beats. What is the resulting beat frequency, in hertz?

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Answer: 5

Answer

The beat frequency produced by the superposition of the two sound waves is 5 Hz5\text{ Hz}.
When two waves of slightly different frequencies interfere, periodic variations in sound intensity called beats occur. The number of beats heard per second is equal to the absolute difference between the frequencies of the two superposing waves: fbeat=f2f1=445 Hz440 Hz=5 Hzf_{\text{beat}} = |f_2 - f_1| = |445\text{ Hz} - 440\text{ Hz}| = 5\text{ Hz}.

Step-by-Step Solution

1
Identify the frequencies of the interfering waves
f1=440 Hzf_1 = 440\text{ Hz} and f2=445 Hzf_2 = 445\text{ Hz}
Beat frequency is determined by the absolute difference between the individual wave frequencies.
2
Subtract the lower frequency from the higher frequency to find the beat frequency
fbeat=445440=5 Hzf_{\text{beat}} = |445 - 440| = 5\text{ Hz}
The rate of periodic intensity variation (beat frequency) is governed by fbeat=f2f1f_{\text{beat}} = |f_2 - f_1|.

Key Concept

Beat Frequency and Wave Superposition
Question 7167Question

In a cathode-ray experiment, a beam of electrons passes undeflected through mutually perpendicular electric and magnetic fields. If the electric field intensity between the deflection plates is 4.0×104 V m14.0 \times 10^{4}\text{ V m}^{-1} and the magnetic flux density is 2.0×103 T2.0 \times 10^{-3}\text{ T}, what is the velocity of the electrons in the cathode-ray beam?

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Answer: 2.0×107 m s12.0 \times 10^{7}\text{ m s}^{-1}

Answer

The velocity of the electrons in the cathode-ray beam is 2.0×107 m s12.0 \times 10^{7}\text{ m s}^{-1}.
For cathode rays passing undeflected through perpendicular electric (EE) and magnetic (BB) fields, the electric force eEeE pulling electrons toward the positive plate is exactly balanced by the magnetic force evBevB. Equating eE=evBeE = evB leads directly to v=EBv = \frac{E}{B}. Substituting E=4.0×104 V m1E = 4.0 \times 10^{4}\text{ V m}^{-1} and B=2.0×103 TB = 2.0 \times 10^{-3}\text{ T} gives v=4.0×1042.0×103=2.0×107 m s1v = \frac{4.0 \times 10^{4}}{2.0 \times 10^{-3}} = 2.0 \times 10^{7}\text{ m s}^{-1}.

Step-by-Step Solution

1
Identify the equilibrium condition for an undeflected electron beam in crossed fields.
The electric force Fe=eEF_e = eE balances the magnetic Lorentz force Fb=evBF_b = evB, so eE=evBeE = evB.
When cathode rays pass undeflected, the net transverse force acting on each electron is zero.
2
Rearrange the equilibrium equation to solve for velocity vv.
v=EBv = \frac{E}{B}
Canceling the elementary charge ee from both sides isolates electron speed as a function of field strengths.
3
Substitute the given values into the velocity equation.
v=4.0×104 V m12.0×103 T=2.0×107 m s1v = \frac{4.0 \times 10^{4}\text{ V m}^{-1}}{2.0 \times 10^{-3}\text{ T}} = 2.0 \times 10^{7}\text{ m s}^{-1}
Executing the division yields the velocity of cathode rays.

Key Concept

Velocity selector principle in crossed electric and magnetic fields (J.J. Thomson cathode ray velocity determination)
Question 7168Question
A function f(x)f(x) is defined by
f(x)={2x25x3x3,x3k+2,x=3f(x) = \begin{cases} \frac{2x^2 - 5x - 3}{x - 3}, & x \neq 3 \\ k + 2, & x = 3 \end{cases}
If f(x)f(x) is continuous at x=3x = 3, what is the value of the constant kk?
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Answer: 55

Answer

The constant value is k=5k = 5.
For the function to be continuous at x=3x = 3, the limit as x3x \to 3 must equal the value of the function at x=3x = 3, which is f(3)=k+2f(3) = k + 2. Factoring the numerator gives 2x25x3=(2x+1)(x3)2x^2 - 5x - 3 = (2x + 1)(x - 3). Canceling the common factor (x3)(x - 3) leaves limx3(2x+1)=7\lim_{x \to 3}(2x + 1) = 7. Setting k+2=7k + 2 = 7 yields k=5k = 5.

Step-by-Step Solution

1
Evaluate the limit of f(x)f(x) as xx approaches 33
\lim_{x \to 3} \frac{2x^2 - 5x - 3}{x - 3} = \lim_{x \to 3} \frac{(2x + 1)(x - 3)}{x - 3} = \lim_{x \to 3} (2x + 1) = 2(3) + 1 = 7
Direct substitution yields the indeterminate form 00\frac{0}{0}, so the numerator must be factored to cancel the common term (x3)(x - 3).
2
Apply the definition of continuity at x=3x = 3
f(3) = \lim_{x \to 3} f(x) \implies k + 2 = 7
For a function to be continuous at a point x=cx = c, the function value f(c)f(c) must equal the limit of f(x)f(x) as xcx \to c.
3
Solve for the constant kk
k = 7 - 2 = 5
Subtract 22 from both sides of the equation.

Key Concept

Continuity of a Piecewise Function at a Point
Question 7169Question

A sample of pure ammonia gas (NH3\text{NH}_3) has a mass of 3.4 g3.4\text{ g}. What is the total number of atoms contained in this sample? [N=14,H=1,NA=6.02×1023 mol1][\text{N} = 14, \text{H} = 1, N_A = 6.02 \times 10^{23}\text{ mol}^{-1}]

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Answer: 4.816×10234.816 \times 10^{23}

Answer

4.816×10234.816 \times 10^{23} atoms
The molar mass of ammonia (NH3\text{NH}_3) is 17 g/mol17\text{ g/mol}. A mass of 3.4 g3.4\text{ g} corresponds to 0.2 moles0.2\text{ moles} of NH3\text{NH}_3 molecules, which contains 1.204×10231.204 \times 10^{23} molecules. Because one molecule of NH3\text{NH}_3 consists of 44 atoms (11 nitrogen atom and 33 hydrogen atoms), multiplying 1.204×10231.204 \times 10^{23} by 44 gives 4.816×10234.816 \times 10^{23} total atoms.

Step-by-Step Solution

1
Calculate the molar mass of ammonia (NH3\text{NH}_3)
Molar Mass=14+3(1)=17 g/mol\text{Molar Mass} = 14 + 3(1) = 17\text{ g/mol}
Molar mass is required to convert sample mass into moles.
2
Calculate the number of moles of NH3\text{NH}_3
Moles=3.4 g17 g/mol=0.2 mol\text{Moles} = \frac{3.4\text{ g}}{17\text{ g/mol}} = 0.2\text{ mol}
Dividing given mass by molar mass yields the mole quantity.
3
Determine the number of molecules of NH3\text{NH}_3
Molecules=0.2 mol×6.02×1023 mol1=1.204×1023 molecules\text{Molecules} = 0.2\text{ mol} \times 6.02 \times 10^{23}\text{ mol}^{-1} = 1.204 \times 10^{23}\text{ molecules}
Multiplying moles by Avogadro's constant gives total molecules.
4
Calculate the total number of individual atoms
Total atoms=1.204×1023×4=4.816×1023 atoms\text{Total atoms} = 1.204 \times 10^{23} \times 4 = 4.816 \times 10^{23}\text{ atoms}
Each NH3\text{NH}_3 molecule contains 1 nitrogen atom and 3 hydrogen atoms (4 atoms in total).

Key Concept

Converting mass to number of constituent atoms using Avogadro's constant and molecular stoichiometry.
Question 7170Question

What is the xx-intercept of the normal line to the curve y=x24x+5y = x^2 - 4x + 5 at the point where x=3x = 3?

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Answer: 7

Answer

The xx-intercept of the normal line is 7.
Differentiating y=x24x+5y = x^2 - 4x + 5 gives dydx=2x4\frac{dy}{dx} = 2x - 4. Substituting x=3x = 3 yields a tangent gradient of 22, so the normal gradient is 12-\frac{1}{2}. The curve passes through (3,2)(3, 2) at x=3x = 3. The equation of the normal is y2=12(x3)y - 2 = -\frac{1}{2}(x - 3), which simplifies to x+2y7=0x + 2y - 7 = 0. Setting y=0y = 0 gives x=7x = 7.

Step-by-Step Solution

1
Find the yy-coordinate corresponding to x=3x = 3
y=324(3)+5=912+5=2y = 3^2 - 4(3) + 5 = 9 - 12 + 5 = 2. The point on the curve is (3,2)(3, 2).
The normal line passes through the specific point of tangency on the curve.
2
Calculate the gradient of the tangent and normal lines at x=3x = 3
dydx=2x4\frac{dy}{dx} = 2x - 4. At x=3x = 3, mt=2(3)4=2m_t = 2(3) - 4 = 2. Therefore, mn=1mt=12m_n = -\frac{1}{m_t} = -\frac{1}{2}.
The normal line is perpendicular to the tangent line.
3
Determine the equation of the normal line
y2=12(x3)    2(y2)=(x3)    x+2y7=0y - 2 = -\frac{1}{2}(x - 3) \implies 2(y - 2) = -(x - 3) \implies x + 2y - 7 = 0.
Use the point-slope form yy1=m(xx1)y - y_1 = m(x - x_1) to write the linear equation.
4
Find the xx-intercept of the normal line
Set y=0y = 0: x+2(0)7=0    x=7x + 2(0) - 7 = 0 \implies x = 7.
The xx-intercept occurs where y=0y = 0.

Key Concept

Tangents and Normals to Curves
Estimated Time:1m 30s
Question 7171Question

A metal surface inside a vacuum cell is illuminated by incident photons each having an energy of 6.2 eV6.2\text{ eV}. If the maximum kinetic energy of the emitted photoelectrons is 2.4 eV2.4\text{ eV}, what is the work function of the metal in electron-volts (eV\text{eV})?

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Answer: 3.8

Answer

The work function of the metal is 3.8 eV3.8\text{ eV}.
According to Einstein's photoelectric equation, the total energy of an incident photon (E=6.2 eVE = 6.2\text{ eV}) equals the work function of the metal (W0W_0) plus the maximum kinetic energy of the ejected photoelectrons (Kmax=2.4 eVK_{\max} = 2.4\text{ eV}). Subtracting the kinetic energy from the photon energy gives W0=6.2 eV2.4 eV=3.8 eVW_0 = 6.2\text{ eV} - 2.4\text{ eV} = 3.8\text{ eV}.

Step-by-Step Solution

1
State Einstein's photoelectric equation
E=W0+KmaxE = W_0 + K_{\max}
Relates the incident photon energy to the metal work function and photoelectron kinetic energy.
2
Rearrange the equation to solve for the work function
W0=EKmaxW_0 = E - K_{\max}
Isolates the work function W0W_0 on one side of the equation.
3
Substitute the given numerical values and compute
W0=6.2 eV2.4 eV=3.8 eVW_0 = 6.2\text{ eV} - 2.4\text{ eV} = 3.8\text{ eV}
Evaluates the difference to obtain the minimum energy needed to remove an electron.

Key Concept

Einstein's Photoelectric Equation and Work Function
Question 7172Question

Power is defined as the rate at which work is done or energy is transferred. Which of the following expressions represents the correct dimensional formula for power?

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Answer: ML2T3M L^2 T^{-3}

Answer

ML2T3M L^2 T^{-3}
Power is defined as work done per unit time (P=WtP = \frac{W}{t}). The dimensional formula for work is [W]=ML2T2[W] = M L^2 T^{-2}, and for time is [t]=T[t] = T. Dividing work by time gives [P]=ML2T2T=ML2T3[P] = \frac{M L^2 T^{-2}}{T} = M L^2 T^{-3}.

Step-by-Step Solution

1
Write the fundamental definition of power in terms of work and time.
Power=WorkTime\text{Power} = \frac{\text{Work}}{\text{Time}}
By definition, power measures the rate of doing work.
2
Determine the dimensions of work.
[Work]=[Force]×[Distance]=(MLT2)×L=ML2T2[\text{Work}] = [\text{Force}] \times [\text{Distance}] = (M L T^{-2}) \times L = M L^2 T^{-2}
Force has dimensions of mass times acceleration (MLT2M L T^{-2}), and multiplying by distance (LL) yields energy or work dimensions.
3
Divide the dimensions of work by the dimension of time (TT).
[Power]=ML2T2T=ML2T3[\text{Power}] = \frac{M L^2 T^{-2}}{T} = M L^2 T^{-3}
Dividing by time increases the negative exponent of time from 2-2 to 3-3.

Key Concept

Dimensional Formula for Power
Question 7173Question

Match each experimental observation of cathode rays in a discharge tube with the corresponding physical property or characteristic it demonstrates.

Click a left item, then click its matching right item

Items

Formation of a sharp shadow when a Maltese cross is placed in the path of the rays
Rotation of a small, lightweight paddle wheel placed along the path of the beam
Deflection of the beam toward a positively charged electric plate
Deflection of the beam in a direction perpendicular to an applied magnetic field

Matches

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Answer

1. Formation of a sharp shadow of a Maltese cross matches with Cathode rays travel in straight lines. 2. Rotation of a paddle wheel matches with Cathode rays possess particle mass and mechanical momentum. 3. Deflection toward a positively charged plate matches with Cathode rays carry a negative electrical charge. 4. Deflection perpendicular to a magnetic field matches with Cathode rays act as a current of moving charged particles obeying magnetic force laws.
Each experimental setup provides specific proof of a cathode ray property: sharp shadow formation proves straight-line motion; turning a paddle wheel demonstrates particle mass and momentum; attraction to a positive plate confirms negative charge; and deflection in a magnetic field confirms that the beam acts as moving electrical charges.

Step-by-Step Solution

1
Analyze the Maltese cross shadow experiment
Sharp shadows indicate straight-line propagation of rays from the cathode surface.
Light and particle beams traveling in straight lines produce sharp geometrical shadows of opaque obstructions.
2
Analyze the paddle wheel experiment
The paddle wheel rotates when struck by cathode rays, demonstrating kinetic energy and momentum transfer.
Mechanical rotation requires a force resulting from the momentum transfer of moving material particles.
3
Analyze electric field deflection
The ray path bends toward the positive anode plate.
Electrostatic attraction pulls negatively charged entities toward positive electric potentials.
4
Analyze magnetic field deflection
The beam bends laterally perpendicular to both the trajectory and the magnetic field vector.
Moving electrical charges experience a magnetic Lorentz force given by F=qvBsinθF = qvB\sin\theta.

Key Concept

Experimental evidence establishing the properties of cathode rays
Estimated Time:1m 30s
Question 7174Question

What is the result of evaluating the indefinite integral ((2x1)26cos(2x))dx\int \left( (2x - 1)^2 - 6\cos(2x) \right) \, dx?

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Answer: 43x32x2+x3sin(2x)+C\frac{4}{3}x^3 - 2x^2 + x - 3\sin(2x) + C

Answer

43x32x2+x3sin(2x)+C\frac{4}{3}x^3 - 2x^2 + x - 3\sin(2x) + C
Expanding the squared term (2x1)2(2x - 1)^2 yields 4x24x+14x^2 - 4x + 1. Integrating term by term using the power rule gives 43x32x2+x\frac{4}{3}x^3 - 2x^2 + x. The integral of 6cos(2x)-6\cos(2x) is 62sin(2x)=3sin(2x)-\frac{6}{2}\sin(2x) = -3\sin(2x). Adding the arbitrary constant CC results in 43x32x2+x3sin(2x)+C\frac{4}{3}x^3 - 2x^2 + x - 3\sin(2x) + C.

Step-by-Step Solution

1
Expand the squared binomial term inside the integral
(2x1)2=4x24x+1(2x - 1)^2 = 4x^2 - 4x + 1
Expanding the expression allows for term-by-term integration using standard integration rules.
2
Integrate each term of the expanded polynomial
\int (4x^2 - 4x + 1) \, dx = \frac{4}{3}x^3 - 2x^2 + x
Apply the power rule for integration: \int x^n \, dx = \frac{x^{n+1}}{n+1}.
3
Integrate the trigonometric term
\int -6\cos(2x) \, dx = -6 \cdot \frac{1}{2}\sin(2x) = -3\sin(2x)
The standard integral of \cos(kx) is \frac{1}{k}\sin(kx).
4
Combine all integrated terms and append the constant of integration
\frac{4}{3}x^3 - 2x^2 + x - 3\sin(2x) + C
Indefinite integration requires an arbitrary constant of integration C.

Key Concept

Indefinite Integration of Polynomial and Trigonometric Functions
Question 7175Question

Which of the following sets contains all values of xx in the interval 0x3600^\circ \le x \le 360^\circ that satisfy the trigonometric equation 3sinx+cosx=0\sqrt{3}\sin x + \cos x = 0?

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Answer: 150 and 330150^\circ \text{ and } 330^\circ

Answer

150 and 330150^\circ \text{ and } 330^\circ
The given equation 3sinx+cosx=0\sqrt{3}\sin x + \cos x = 0 simplifies to tanx=13\tan x = -\frac{1}{\sqrt{3}}. Since tangent is negative in the second and fourth quadrants with a reference angle of 3030^\circ, the solutions in the domain 0x3600^\circ \le x \le 360^\circ are 18030=150180^\circ - 30^\circ = 150^\circ and 36030=330360^\circ - 30^\circ = 330^\circ.

Step-by-Step Solution

1
Rearrange the trigonometric equation into single ratio form
3sinx=cosx    sinxcosx=13    tanx=13\sqrt{3}\sin x = -\cos x \implies \frac{\sin x}{\cos x} = -\frac{1}{\sqrt{3}} \implies \tan x = -\frac{1}{\sqrt{3}}
Dividing both sides by cosx\cos x converts the sum of sine and cosine terms into a simple tangent equation.
2
Determine the reference angle
Reference angle α=30\text{Reference angle } \alpha = 30^\circ
The acute angle whose tangent is 13\frac{1}{\sqrt{3}} is 3030^\circ.
3
Identify the quadrants and find all solutions in 0x3600^\circ \le x \le 360^\circ
x=18030=150x = 180^\circ - 30^\circ = 150^\circ (Quadrant II) and x=36030=330x = 360^\circ - 30^\circ = 330^\circ (Quadrant IV)
The tangent function is negative in Quadrants II and IV.

Key Concept

Solving simple trigonometric equations by reducing to a basic ratio and finding all solutions within a given domain.
Estimated Time:1m 30s
Question 7176Question

Match each physical quantity on the left with its correct fundamental SI base unit expression or fundamental status on the right.

Click a left item, then click its matching right item

Items

Thermodynamic temperature
Electric charge
Linear momentum
Power

Matches

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Answer

Thermodynamic temperature matches with 'Fundamental physical quantity measured in kelvin (K)'; Electric charge matches with 'Derived physical quantity expressed in base SI units as A·s'; Linear momentum matches with 'Derived physical quantity expressed in base SI units as kg·m·s⁻¹'; Power matches with 'Derived physical quantity expressed in base SI units as kg·m²·s⁻³'.
Each physical quantity is correctly paired with either its fundamental status or its base SI unit breakdown derived from core physics definitions.

Step-by-Step Solution

1
Identify fundamental quantities versus derived quantities.
Thermodynamic temperature is a basic fundamental quantity (unit: K\text{K}). Electric current is fundamental (unit: A\text{A}), but electric charge is derived (Q=ItQ = I t).
Fundamental quantities cannot be defined in terms of other physical quantities.
2
Decompose Electric Charge into base units.
Since Q=ItQ = I \cdot t, its unit is As\text{A}\cdot\text{s}.
Current is measured in amperes and time in seconds.
3
Decompose Linear Momentum into base units.
p=mvunit=kgms1p = m \cdot v \Rightarrow \text{unit} = \text{kg} \cdot \text{m}\cdot\text{s}^{-1}.
Mass is in kilograms and velocity is in meters per second.
4
Decompose Power into base units.
P=Wt=Fdt=(ma)dtkg(ms2)ms=kgm2s3P = \frac{W}{t} = \frac{F \cdot d}{t} = \frac{(m \cdot a) \cdot d}{t} \Rightarrow \frac{\text{kg} \cdot (\text{m}\cdot\text{s}^{-2}) \cdot \text{m}}{\text{s}} = \text{kg}\cdot\text{m}^2\cdot\text{s}^{-3}.
Power is work done per unit time.

Key Concept

Fundamental and Derived Quantities
Question 7177Question

Increasing the intensity of incident monochromatic light of a fixed frequency above the threshold frequency increases the maximum kinetic energy of the photoelectrons emitted from a metal surface.

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Answer: False

Answer

The statement is False. Increasing light intensity at constant frequency increases the number of emitted photoelectrons per second (photoelectric current), but leaves their maximum kinetic energy unchanged.
The statement is false. In quantum physics, increasing the intensity of monochromatic light increases the photon flux, which elevates the rate of photoelectron emission (photoelectric current). However, the maximum kinetic energy of each photoelectron depends solely on the energy of an individual photon (E=hfE = hf) minus the metal's work function (W0W_0), both of which remain unchanged when intensity is increased at fixed frequency.

Step-by-Step Solution

1
Identify the factors determining maximum kinetic energy in the photoelectric effect.
Maximum kinetic energy KmaxK_{\text{max}} is governed by Einstein's photoelectric equation Kmax=hfW0K_{\text{max}} = hf - W_0.
Energy transfer occurs on a one-photon-to-one-electron basis.
2
Determine the physical quantity affected by changing light intensity.
Intensity dictates the number of photons striking the metal surface per unit time.
Higher intensity means a greater photon flux, which increases the photoelectron emission rate.
3
Evaluate the statement.
The statement falsely attributes an increase in kinetic energy to an increase in intensity.
Since photon frequency ff and work function W0W_0 remain constant, KmaxK_{\text{max}} does not change.

Key Concept

Independence of photoelectron kinetic energy from light intensity
Question 7178Question

A beaker containing water of density 1000 kg/m31000\text{ kg/m}^3 rests on a digital weighing scale, giving an initial reading of 1.50 kg1.50\text{ kg}. A solid aluminum block of mass 0.80 kg0.80\text{ kg} and density 2500 kg/m32500\text{ kg/m}^3 is suspended from a string and completely immersed in the water without touching the bottom or sides of the beaker. What is the new reading on the digital weighing scale, in kilograms? (Take g=10 m/s2g = 10\text{ m/s}^2)

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Answer: 1.82

Answer

The new reading on the digital weighing scale is 1.82 kg1.82\text{ kg}.
When the aluminum block is fully submerged in the water, it displaces a volume of water equal to its own volume (V=0.802500=3.2×104 m3V = \frac{0.80}{2500} = 3.2 \times 10^{-4}\text{ m}^3). The mass of this displaced water is mwater=1000×3.2×104=0.32 kgm_{\text{water}} = 1000 \times 3.2 \times 10^{-4} = 0.32\text{ kg}. The upthrust exerted by the water upward on the block is equal to the weight of the displaced water (3.2 N3.2\text{ N}). By Newton's Third Law, the block exerts an equal and opposite downward reaction force (3.2 N3.2\text{ N}) on the water. This extra downward force adds an equivalent mass of 0.32 kg0.32\text{ kg} to the digital scale reading, making the new reading 1.50 kg+0.32 kg=1.82 kg1.50\text{ kg} + 0.32\text{ kg} = 1.82\text{ kg}.

Step-by-Step Solution

1
Calculate the volume of the submerged block
Volume V=3.2×104 m3V = 3.2 \times 10^{-4}\text{ m}^3
The volume of fluid displaced by a completely submerged body equals the volume of the body itself.
2
Find the mass of the displaced water
Mass of displaced water mwater=0.32 kgm_{\text{water}} = 0.32\text{ kg}
According to Archimedes' principle, the upthrust equals the weight of the displaced fluid, which corresponds to a displaced mass of ρwaterV\rho_{\text{water}} V.
3
Apply Newton's Third Law to determine the change in scale reading
Scale reading increase Δm=0.32 kg\Delta m = 0.32\text{ kg}
The fluid exerts an upward buoyant force on the block, so by Newton's Third Law, the block exerts an equal downward reaction force on the fluid, transferring an effective weight equal to the upthrust onto the scale.
4
Compute the total new scale reading
New scale reading =1.82 kg= 1.82\text{ kg}
Sum the initial mass reading of the beaker system (1.50 kg1.50\text{ kg}) and the mass of the displaced water (0.32 kg0.32\text{ kg}).

Key Concept

Apparent weight transfer, Archimedes' principle, and Newton's Third Law
Question 7179Question

Match each kinetic theory concept on the left with its correct physical description on the right.

Click a left item, then click its matching right item

Items

Temperature of a gas
Pressure of a gas
Root-mean-square speed

Matches

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Answer

Temperature matches with the measure of average translational kinetic energy; Pressure matches with the average force per unit area exerted by colliding gas molecules on container walls; Root-mean-square speed matches with the square root of the mean of squared speeds.
Temperature measures average translational kinetic energy per particle. Pressure originates from force per unit area due to elastic wall collisions. Root-mean-square speed is the square root of the mean of squared molecular speeds.

Step-by-Step Solution

1
Identify the kinetic theory definition of Temperature
Temperature is directly proportional to the mean translational kinetic energy of the gas particles (EkTE_k \propto T).
Absolute temperature reflects the average kinetic energy of molecular motion.
2
Identify the microscopic origin of Gas Pressure
Pressure is caused by molecular collisions with the container walls, transferring momentum and creating force per unit area.
Frequent elastic collisions of particles on container walls produce measurable pressure.
3
Identify the mathematical definition of Root-Mean-Square Speed
vrms=v2v_{rms} = \sqrt{\overline{v^2}}, representing the square root of the average of squared molecular velocities.
This parameter represents the effective speed of gas particles relevant to thermal kinetic energy.

Key Concept

Kinetic Theory Interpretation of Gas Properties
Question 7180Question

A convex mirror forms an upright image that is 13\frac{1}{3} the size of an object. When the object is moved 20 cm20\text{ cm} further away from the mirror, the size of the image becomes 15\frac{1}{5} the size of the object. What is the radius of curvature of the mirror?

Show answer & explanation

Answer: 20 cm20\text{ cm}

Answer

The radius of curvature of the convex mirror is 20 cm20\text{ cm}.
For a convex mirror, the focal length is negative (f=f0f = -f_0). The magnification formula m=ffum = \frac{f}{f - u} for a virtual upright image gives m=f0f0u=f0f0+um = \frac{-f_0}{-f_0 - u} = \frac{f_0}{f_0 + u}. For m1=13m_1 = \frac{1}{3}, we get u1=2f0u_1 = 2f_0. For m2=15m_2 = \frac{1}{5}, we get u2=4f0u_2 = 4f_0. The object displacement is u2u1=2f0=20 cmu_2 - u_1 = 2f_0 = 20\text{ cm}, which gives f0=10 cmf_0 = 10\text{ cm}. The radius of curvature is R=2f0=20 cmR = 2f_0 = 20\text{ cm}, making the choice stating 20 cm20\text{ cm} correct.

Step-by-Step Solution

1
Apply the magnification formula and sign convention for a convex mirror at the first position.
For a convex mirror, f=f0f = -f_0 and the image is virtual (v1=v01v_1 = -v_{01}). Magnification m1=v1u1=v01u1=13m_1 = -\frac{v_1}{u_1} = \frac{v_{01}}{u_1} = \frac{1}{3}, so v01=u13v_{01} = \frac{u_1}{3}.
Convex mirrors always form virtual, upright, and diminished images.
2
Substitute v1v_1 into the mirror equation for the first position to express u1u_1 in terms of focal length magnitude f0f_0.
1f0=1u1+1v01=1u13u1=2u1    u1=2f0\frac{1}{-f_0} = \frac{1}{u_1} + \frac{1}{-v_{01}} = \frac{1}{u_1} - \frac{3}{u_1} = -\frac{2}{u_1} \implies u_1 = 2f_0.
The mirror formula is 1f=1u+1v\frac{1}{f} = \frac{1}{u} + \frac{1}{v} with cartesian sign conventions.
3
Repeat the mirror equation calculation for the second object position.
For m2=15m_2 = \frac{1}{5}, v02=u25v_{02} = \frac{u_2}{5}. Substituting gives 1f0=1u25u2=4u2    u2=4f0\frac{1}{-f_0} = \frac{1}{u_2} - \frac{5}{u_2} = -\frac{4}{u_2} \implies u_2 = 4f_0.
The second object position gives a magnification of 15\frac{1}{5}.
4
Use the known object shift distance to solve for f0f_0 and radius of curvature RR.
u2u1=20 cm    4f02f0=20 cm    2f0=20 cm    f0=10 cmu_2 - u_1 = 20\text{ cm} \implies 4f_0 - 2f_0 = 20\text{ cm} \implies 2f_0 = 20\text{ cm} \implies f_0 = 10\text{ cm}. Since R=2f0R = 2f_0, R=20 cmR = 20\text{ cm}.
The distance between the two object positions is 20 cm20\text{ cm}, and the radius of curvature of a spherical mirror is twice its focal length.

Key Concept

Spherical Mirror Formula and Sign Conventions for Convex Mirrors
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