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Question 12841Question

Match each characteristic functional group structure listed on the left with its corresponding organic class name on the right.

Click a left item, then click its matching right item

Items

NH2-\text{NH}_2
CONH2-\text{CONH}_2
O-\text{O}-
COOR-\text{COOR}

Matches

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Answer

The correct pairings are: NH2-\text{NH}_2 matches with Primary amine, CONH2-\text{CONH}_2 matches with Amide, O-\text{O}- matches with Ether, and COOR-\text{COOR} matches with Ester.
Each organic compound class is identified by its specific functional group arrangement: NH2-\text{NH}_2 specifies primary amines, CONH2-\text{CONH}_2 specifies primary amides, an oxygen atom bridging two carbon groups (O-\text{O}-) specifies ethers, and COOR-\text{COOR} specifies esters.

Step-by-Step Solution

1
Identify the amino functional group
NH2-\text{NH}_2 is recognized as an amino group attached to a carbon chain.
Compounds containing the NH2-\text{NH}_2 group attached directly to an alkyl carbon belong to the class of primary amines.
2
Identify the carboxamide functional group
CONH2-\text{CONH}_2 contains a carbonyl bonded to an amino group.
This structural unit defines the primary amide family.
3
Identify the ether linkage
O-\text{O}- represents a single oxygen atom bridging two carbon atoms.
An oxygen atom connected to two alkyl or aryl groups (R-O-R’\text{R-O-R'}) characterizes an ether.
4
Identify the ester group
COOR-\text{COOR} contains a carbonyl carbon attached to an alkoxy group.
This group is derived from an alkanoic acid and an alkanol, forming an ester.

Key Concept

Identification of characteristic functional groups in organic compounds
Question 12842Question

A neutral copper atom undergoes oxidation to form a copper(II) ion, Cu2+Cu^{2+}. Given that the atomic number of copper (CuCu) is 29, which of the following represents the correct ground-state electronic configuration of Cu2+Cu^{2+}?

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Answer: 1s22s22p63s23p63d91s^2 2s^2 2p^6 3s^2 3p^6 3d^9

Answer

The correct ground-state electronic configuration of the copper(II) ion (Cu2+Cu^{2+}) is 1s22s22p63s23p63d91s^2 2s^2 2p^6 3s^2 3p^6 3d^9.
The correct option correctly applies the rules of electronic configuration for transition metals. Neutral copper (Z=29Z=29) has an ground state of 1s22s22p63s23p63d104s11s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^1. When ionized to Cu2+Cu^{2+}, two electrons are removed: the outermost 4s14s^1 electron is lost first, followed by one electron from the 3d103d^{10} subshell, leaving 1s22s22p63s23p63d91s^2 2s^2 2p^6 3s^2 3p^6 3d^9.

Step-by-Step Solution

1
Determine the total number of electrons in neutral copper (CuCu) and write its ground-state configuration.
Atomic number Z=29Z = 29, so neutral CuCu has 29 electrons. Due to the extra stability of a completely filled dd-subshell, the configuration is 1s22s22p63s23p63d104s11s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^1.
Full subshell stability causes one electron from the 4s4s orbital to promote to the 3d3d subshell in neutral copper.
2
Calculate the number of electrons lost to form the Cu2+Cu^{2+} ion.
Cu2+Cu^{2+} loses 2 electrons, leaving 292=2729 - 2 = 27 electrons.
A +2+2 charge indicates the loss of two valence electrons.
3
Remove two electrons following the rule for transition metal cation formation.
Remove the 1 electron from the outermost 4s4s orbital first, then 1 electron from the 3d3d orbital, leaving 3d93d^9.
Electrons in the highest principal energy level (n=4n=4) are lost before inner (n1)d(n-1)d electrons (n=3n=3).

Key Concept

Electronic configuration of d-block cations
Estimated Time:1m 0s
Question 12843Question

In the industrial synthesis of sodium trioxocarbonate(IV) via the Solvay process, ammonia gas is recovered and continuously recycled within the manufacturing loop. Which two naturally occurring raw materials are consumed as the primary starting feedstocks, making proximity to their natural deposits the key siting factor for the plant?

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Answer: Brine (concentrated sodium chloride) and limestone (calcium carbonate)

Answer

Brine (concentrated sodium chloride) and limestone (calcium carbonate) are the primary naturally occurring raw materials consumed in the Solvay process.
The Solvay process for manufacturing sodium trioxocarbonate(IV) (soda ash) requires concentrated sodium chloride solution (brine) and calcium carbonate (limestone) as primary, naturally occurring starting raw materials. Because these materials are heavy and consumed in bulk, factories are sited near salt deposits/sea coast and limestone quarries to minimize freight costs.

Step-by-Step Solution

1
Identify the chemical reactions and overall stoichiometry of the Solvay process.
The overall chemical reaction is 2NaCl+CaCO3Na2CO3+CaCl22\text{NaCl} + \text{CaCO}_3 \rightarrow \text{Na}_2\text{CO}_3 + \text{CaCl}_2.
Understanding the net balanced equation shows which substances are consumed as starting reactants.
2
Distinguish between primary naturally occurring raw materials, intermediates/reagents, and by-products.
Brine (NaCl\text{NaCl}) and limestone (CaCO3\text{CaCO}_3) are directly extracted natural resources consumed in massive quantities. Ammonia (NH3\text{NH}_3) is recycled internally.
Heavy chemical industries are sited near bulky primary raw material deposits to minimize raw material transportation costs.

Key Concept

Solvay Process Raw Materials and Siting Factors
Estimated Time:1m 0s
Question 12844Question
In a nuclear fusion reaction, a deuterium nucleus (12H{^{2}_{1}\text{H}}) fuses with a tritium nucleus (13H{^{3}_{1}\text{H}}) according to the equation:
12H+13H24He+01n+Q{^{2}_{1}\text{H}} + {^{3}_{1}\text{H}} \rightarrow {^{4}_{2}\text{He}} + {^{1}_{0}\text{n}} + Q

Given the atomic masses:
- Mass of 12H=2.0141 u{^{2}_{1}\text{H}} = 2.0141\text{ u}
- Mass of 13H=3.0160 u{^{3}_{1}\text{H}} = 3.0160\text{ u}
- Mass of 24He=4.0026 u{^{4}_{2}\text{He}} = 4.0026\text{ u}
- Mass of 01n=1.0087 u{^{1}_{0}\text{n}} = 1.0087\text{ u}
- 1 u=931.5 MeV1\text{ u} = 931.5\text{ MeV}

What is the total energy QQ released in this reaction?

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Answer: 17.51 MeV17.51\text{ MeV}

Answer

The total energy released in the reaction is 17.51 MeV17.51\text{ MeV}.
The correct answer of 17.51 MeV17.51\text{ MeV} is obtained by subtracting the combined mass of the helium-4 nucleus and neutron (5.0113 u5.0113\text{ u}) from the combined mass of the deuterium and tritium nuclei (5.0301 u5.0301\text{ u}) to yield a mass defect of 0.0188 u0.0188\text{ u}, which equates to 17.51 MeV17.51\text{ MeV} when multiplied by 931.5 MeV/u931.5\text{ MeV/u}.

Step-by-Step Solution

1
Calculate the total mass of the reactants before the fusion reaction.
Mass of reactants=2.0141 u+3.0160 u=5.0301 u\text{Mass of reactants} = 2.0141\text{ u} + 3.0160\text{ u} = 5.0301\text{ u}
To find the mass defect, we must first sum the masses of the initial nuclei.
2
Calculate the total mass of the reaction products.
Mass of products=4.0026 u+1.0087 u=5.0113 u\text{Mass of products} = 4.0026\text{ u} + 1.0087\text{ u} = 5.0113\text{ u}
The products include both the helium-4 nucleus and the emitted neutron.
3
Determine the mass defect (Δm\Delta m).
Δm=5.0301 u5.0113 u=0.0188 u\Delta m = 5.0301\text{ u} - 5.0113\text{ u} = 0.0188\text{ u}
The mass defect represents the mass converted into energy during fusion.
4
Convert the mass defect into released energy QQ in MeV\text{MeV}.
Q=0.0188 u×931.5 MeV/u=17.5122 MeV17.51 MeVQ = 0.0188\text{ u} \times 931.5\text{ MeV/u} = 17.5122\text{ MeV} \approx 17.51\text{ MeV}
Using Einstein's mass-energy equivalence with 1 u=931.5 MeV1\text{ u} = 931.5\text{ MeV}.

Key Concept

Mass defect and energy release in nuclear fusion reactions
Estimated Time:1m 30s
Question 12845Question

A light ray traveling inside a transparent glass prism of refractive index 1.501.50 strikes the boundary with air. What is the sine of the critical angle (sinC\sin C) for total internal reflection to occur at this boundary?

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Answer: 0.670.67

Answer

The sine of the critical angle (sinC\sin C) for total internal reflection at the glass-air boundary is 0.670.67.
For light moving from a medium with refractive index nn into air, total internal reflection occurs when the angle of incidence exceeds the critical angle CC. The critical angle satisfies sinC=1n\sin C = \frac{1}{n}. Substituting n=1.50n = 1.50 gives sinC=11.50=0.67\sin C = \frac{1}{1.50} = 0.67.

Step-by-Step Solution

1
Identify the relationship between the refractive index (nn) and the critical angle (CC) when light travels from a medium to air.
sinC=1n\sin C = \frac{1}{n}
By Snell's law, at the critical angle of incidence, the angle of refraction in air is 9090^\circ (so sin90=1\sin 90^\circ = 1).
2
Substitute the given refractive index (n=1.50n = 1.50) into the formula.
sinC=11.50=230.67\sin C = \frac{1}{1.50} = \frac{2}{3} \approx 0.67
Dividing 11 by 1.501.50 yields 0.666...0.666..., which rounds to 0.670.67.

Key Concept

Critical Angle and Total Internal Reflection
Estimated Time:45s
Question 12846Question

According to the kinetic theory of gases, the average kinetic energy of gas molecules is directly proportional to the absolute temperature. If a sample of nitrogen gas at an initial temperature of 27C27^\circ\text{C} is heated until the average kinetic energy of its molecules is tripled, what is the final temperature of the gas in C^\circ\text{C}?

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Answer: 627C627^\circ\text{C}

Answer

The final temperature of the gas is 627C627^\circ\text{C}.
According to the kinetic theory of gases, the average kinetic energy of gas particles is directly proportional to the absolute temperature in Kelvin (EkTE_k \propto T). Converting the initial temperature 27C27^\circ\text{C} to Kelvin yields 27+273=300 K27 + 273 = 300\text{ K}. Tripling the average kinetic energy means tripling the absolute temperature to 3×300 K=900 K3 \times 300\text{ K} = 900\text{ K}. Converting this back to degrees Celsius gives 900273=627C900 - 273 = 627^\circ\text{C}.

Step-by-Step Solution

1
Convert the initial temperature from Celsius to Kelvin.
T1=27C+273=300 KT_1 = 27^\circ\text{C} + 273 = 300\text{ K}
Kinetic molecular theory states that average kinetic energy is directly proportional to absolute temperature (EkTE_k \propto T in Kelvin).
2
Calculate the new absolute temperature after tripling the kinetic energy.
T2=3×T1=3×300 K=900 KT_2 = 3 \times T_1 = 3 \times 300\text{ K} = 900\text{ K}
Tripling the average kinetic energy directly triples the absolute temperature in Kelvin.
3
Convert the final absolute temperature back to degrees Celsius.
t2=900 K273=627Ct_2 = 900\text{ K} - 273 = 627^\circ\text{C}
The question explicitly requests the final temperature in degrees Celsius (t=T273t = T - 273).

Key Concept

Relationship between average kinetic energy and absolute temperature in the kinetic molecular theory
Question 12847Question

A uniform rigid beam MNMN of length 2.0 m2.0\text{ m} and weight 80 N80\text{ N} is smoothly pivoted at end MM. A vertical load of 120 N120\text{ N} is hung at a distance of 1.5 m1.5\text{ m} from MM. The beam is held horizontally in equilibrium by a cable attached at end NN pulling upward at an angle of 3030^\circ to the horizontal beam. What is the magnitude of the tension in the cable?

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Answer: 260 N260\text{ N}

Answer

The magnitude of the tension in the cable is 260 N260\text{ N}.
For rotational equilibrium about pivot MM, the sum of clockwise moments must equal the counterclockwise moment. Clockwise moment from the beam's weight and load is (80 N×1.0 m)+(120 N×1.5 m)=260 Nm(80\text{ N} \times 1.0\text{ m}) + (120\text{ N} \times 1.5\text{ m}) = 260\text{ N}\cdot\text{m}. Counterclockwise moment from the cable tension is T×2.0 m×sin(30)=1.0T NmT \times 2.0\text{ m} \times \sin(30^\circ) = 1.0 T\text{ N}\cdot\text{m}. Equating the two gives T=260 NT = 260\text{ N}.

Step-by-Step Solution

1
Identify the positions and lines of action of all forces relative to pivot MM.
The weight of the uniform beam (80 N80\text{ N}) acts at its center of gravity (1.0 m1.0\text{ m} from MM). The suspended load (120 N120\text{ N}) acts at 1.5 m1.5\text{ m} from MM. Cable tension TT acts at 2.0 m2.0\text{ m} from MM at an angle of 3030^\circ to the beam.
Rotational equilibrium requires evaluating moments created by all forces about the pivot point.
2
Calculate the sum of clockwise moments about pivot MM.
τclockwise=(80 N×1.0 m)+(120 N×1.5 m)=80 Nm+180 Nm=260 Nm\sum \tau_{\text{clockwise}} = (80\text{ N} \times 1.0\text{ m}) + (120\text{ N} \times 1.5\text{ m}) = 80\text{ N}\cdot\text{m} + 180\text{ N}\cdot\text{m} = 260\text{ N}\cdot\text{m}.
Both downward forces exert clockwise turning effects about pivot MM.
3
Determine the counterclockwise moment exerted by the inclined cable tension TT.
\tau_{\text{counterclockwise}} = T \times d \sin\theta = T \times 2.0\text{ m} \times \sin(30^\circ) = 1.0 T\text{ N}\cdot\text{m}.
Only the component of tension perpendicular to the beam (Tsin30T \sin 30^\circ) produces a moment about the pivot.
4
Apply the Principle of Moments to calculate tension TT.
1.0 T = 260 \implies T = 260\text{ N}.
For the beam to remain horizontally balanced, total clockwise moment must equal total counterclockwise moment.

Key Concept

Principle of Moments and Rotational Equilibrium with Inclined Forces
Question 12848Question

An object of mass 4 kg4\text{ kg} is released from rest at a height of 5 m5\text{ m} above the ground. Neglecting air resistance and taking g=10 m s2g = 10\text{ m s}^{-2}, what is its kinetic energy just before striking the ground?

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Answer: 200 J200\text{ J}

Answer

The kinetic energy of the object just before striking the ground is 200 J200\text{ J}.
The total mechanical energy is conserved during free fall. The initial gravitational potential energy Ep=mgh=4×10×5=200 JE_p = mgh = 4 \times 10 \times 5 = 200\text{ J} is completely converted into kinetic energy EkE_k just before impact, making 200 J200\text{ J} the correct answer.

Step-by-Step Solution

1
Calculate the initial potential energy at maximum height
Ep=mgh=4 kg×10 m s2×5 m=200 JE_p = mgh = 4\text{ kg} \times 10\text{ m s}^{-2} \times 5\text{ m} = 200\text{ J}
At the top of the fall, all mechanical energy is stored as gravitational potential energy.
2
Apply the principle of conservation of mechanical energy
Ek=Ep=200 JE_k = E_p = 200\text{ J}
In the absence of resistive forces such as air drag, potential energy lost converts completely into kinetic energy gained.

Key Concept

Conservation of Mechanical Energy
Estimated Time:45s
Question 12849Question

Match each organic functional group class on the left with its corresponding characteristic IUPAC suffix on the right.

Click a left item, then click its matching right item

Items

Carboxylic acid (COOH-\text{COOH})
Acid amide (CONH2-\text{CONH}_2)
Acyl chloride (COCl-\text{COCl})
Ester (COOR-\text{COOR})

Matches

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Answer

Carboxylic acid matches '-oic acid', Acid amide matches '-amide', Acyl chloride matches '-oyl chloride', and Ester matches '-oate'.
Each organic class is correctly matched to its IUPAC principal suffix: carboxylic acids use '-oic acid', amides use '-amide', acyl chlorides use '-oyl chloride', and esters use '-oate'.

Step-by-Step Solution

1
Identify the characteristic functional group structure for each carbonyl derivative class.
Carboxylic acids have COOH-\text{COOH}, amides have CONH2-\text{CONH}_2, acyl chlorides have COCl-\text{COCl}, and esters have COOR-\text{COOR}.
Functional groups define the chemical family and dictate IUPAC naming rules.
2
Pair each class with its designated IUPAC principal suffix.
COOH-oic acid-\text{COOH} \rightarrow \text{-oic acid}, CONH2-amide-\text{CONH}_2 \rightarrow \text{-amide}, COCl-oyl chloride-\text{COCl} \rightarrow \text{-oyl chloride}, and COOR-oate-\text{COOR} \rightarrow \text{-oate}.
Standard IUPAC rules assign specific characteristic suffixes to represent the main functional group in systematic names.

Key Concept

IUPAC Nomenclature Suffixes for Carbonyl Derivatives
Question 12850Question

A thin converging lens of focal length 15 cm15\text{ cm} forms an erect image that is magnified three times. What is the distance of the object from the lens?

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Answer: 10 cm10\text{ cm}

Answer

10 cm10\text{ cm}
An erect image produced by a thin converging lens is virtual, which means the linear magnification is positive (m=+3m = +3) and the image distance is negative relative to the real object (v=3uv = -3u). Substituting f=+15 cmf = +15\text{ cm} and v=3uv = -3u into the thin lens formula 1f=1u+1v\frac{1}{f} = \frac{1}{u} + \frac{1}{v} gives 115=1u13u=23u\frac{1}{15} = \frac{1}{u} - \frac{1}{3u} = \frac{2}{3u}. Solving for uu yields u=10 cmu = 10\text{ cm}.

Step-by-Step Solution

1
Determine the nature of the image and establish the relationship between image distance and object distance
Since the image formed by a converging lens is erect, it must be virtual. Thus, linear magnification m=+3=vum = +3 = -\frac{v}{u}, giving v=3uv = -3u.
A single convex lens produces an erect image only when the image is virtual, requiring a negative image distance under standard optical sign conventions.
2
Substitute focal length and image distance into the thin lens formula
\frac{1}{f} = \frac{1}{u} + \frac{1}{v} \implies \frac{1}{15} = \frac{1}{u} + \frac{1}{-3u}
The thin lens equation relates focal length, object distance, and image distance.
3
Simplify the algebraic expression and solve for object distance u
\frac{1}{15} = \frac{3 - 1}{3u} = \frac{2}{3u} \implies 3u = 30 \implies u = 10\text{ cm}
Finding a common denominator allows direct solution for the object distance uu.

Key Concept

Thin lens formula and sign conventions for virtual images
Question 12851Question

A particle moves along a circular track of radius rr with a constant speed vv. If the radius of the track is measured with a percentage error of 1.2%1.2\%, and the speed is measured as (10.0±0.3) m s1(10.0 \pm 0.3)\text{ m s}^{-1}, what is the percentage error in the calculated centripetal acceleration of the particle?

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Answer: 7.2

Answer

The percentage error in the calculated centripetal acceleration is 7.2%.
The centripetal acceleration is ac=v2ra_c = \frac{v^2}{r}. The percentage error in vv is 0.310.0×100%=3.0%\frac{0.3}{10.0} \times 100\% = 3.0\%. According to error propagation rules, the percentage error in aca_c is 2×(percentage error in v)+(percentage error in r)=2(3.0%)+1.2%=7.2%2 \times (\text{percentage error in } v) + (\text{percentage error in } r) = 2(3.0\%) + 1.2\% = 7.2\%.

Step-by-Step Solution

1
Calculate the percentage error in the speed measurement vv.
Percentage error in v=0.310.0×100%=3.0%\text{Percentage error in } v = \frac{0.3}{10.0} \times 100\% = 3.0\%
Percentage error is given by dividing the absolute error by the measured value and multiplying by 100%.
2
Write the relationship for centripetal acceleration aca_c in terms of vv and rr.
ac=v2ra_c = \frac{v^2}{r}
Centripetal acceleration is directly proportional to the square of speed and inversely proportional to radius.
3
Apply the fractional error propagation law for a quantity involving powers and quotients.
Δacac=2(Δvv)+Δrr\frac{\Delta a_c}{a_c} = 2\left(\frac{\Delta v}{v}\right) + \frac{\Delta r}{r}
When a measured quantity is raised to a power nn, its fractional error contribution is multiplied by nn. Errors accumulate additively.
4
Substitute the individual percentage errors to find the total percentage error in aca_c.
Percentage error in ac=2(3.0%)+1.2%=7.2%\text{Percentage error in } a_c = 2(3.0\%) + 1.2\% = 7.2\%
Multiplying the speed's percentage error by 2 and adding the radius percentage error yields the total relative error.

Key Concept

Propagation of percentage errors in physical formulas containing powers and ratios.
Question 12852Question

For a fixed mass of an ideal gas held under isothermal conditions, a graph of pressure (PP) plotted against inverse volume (1V\frac{1}{V}) forms a straight line passing through the origin, whose slope increases proportionally with an increase in the system's absolute temperature.

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Answer: True

Answer

The statement is true because the mathematical formulation of Boyle's Law extended by the ideal gas relation, P=(nRT)(1V)P = (nRT)\left(\frac{1}{V}\right), matches the linear equation y=mxy = mx where the slope m=nRTm = nRT is directly proportional to the absolute temperature TT.
The statement accurately reflects the mathematical structure of Boyle's Law under ideal gas behavior. Expressing pressure as P=(nRT)(1V)P = (nRT)\left(\frac{1}{V}\right) shows that a plot of PP versus 1V\frac{1}{V} yields a straight line with y-intercept at zero and slope equal to nRTnRT. Because the slope is directly proportional to absolute temperature TT, raising the temperature increases the gradient of the resulting line.

Step-by-Step Solution

1
Express Boyle's Law incorporating absolute temperature
PV=nRT    P=(nRT)(1V)PV = nRT \implies P = (nRT)\left(\frac{1}{V}\right)
Relate pressure, volume, and absolute temperature mathematically for a fixed mass of gas.
2
Compare the equation to the standard straight-line equation y=mx+cy = mx + c
y=Py = P, x=1Vx = \frac{1}{V}, slope m=nRTm = nRT, and y-intercept c=0c = 0
Determine the graphical relationship when PP is plotted against 1V\frac{1}{V}.
3
Analyze the dependence of the slope on absolute temperature
Since nn (moles of gas) and RR (molar gas constant) are fixed, mTm \propto T
Evaluate how increasing absolute temperature affects the gradient of the isotherm.

Key Concept

Boyle's Law Graphical Representation and Slope-Temperature Relationship
Question 12853Question

An electron of mass 9.0×1031 kg9.0 \times 10^{-31}\text{ kg} and charge 1.6×1019 C1.6 \times 10^{-19}\text{ C} is accelerated from rest through an electric potential difference VV. If the associated de Broglie wavelength of the electron is 1.1×1010 m1.1 \times 10^{-10}\text{ m} and Planck's constant is 6.6×1034 J s6.6 \times 10^{-34}\text{ J s}, what is the value of the potential difference VV?

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Answer: 125 V125\text{ V}

Answer

The accelerating potential difference required is 125 V125\text{ V}.
The de Broglie wavelength of an electron accelerated from rest through a potential difference VV is given by λ=h2meV\lambda = \frac{h}{\sqrt{2meV}}. Rearranging for VV gives V=h22meλ2V = \frac{h^2}{2me\lambda^2}. Substituting h=6.6×1034 J sh = 6.6 \times 10^{-34}\text{ J s}, m=9.0×1031 kgm = 9.0 \times 10^{-31}\text{ kg}, e=1.6×1019 Ce = 1.6 \times 10^{-19}\text{ C}, and λ=1.1×1010 m\lambda = 1.1 \times 10^{-10}\text{ m} gives V=125 VV = 125\text{ V}.

Step-by-Step Solution

1
Relate kinetic energy to momentum and accelerating potential.
Ek=eVE_k = eV and p=2mEk=2meVp = \sqrt{2m E_k} = \sqrt{2meV}
An electron accelerated through potential VV gains kinetic energy equal to eVeV.
2
Substitute momentum into the de Broglie wavelength equation.
\(\lambda = \frac{h}{p} = \frac{h}{\sqrt{2meV}}\)
De Broglie wavelength is defined as Planck's constant divided by momentum.
3
Rearrange the equation to solve for potential difference VV.
\(V = \frac{h^2}{2me\lambda^2}\)
Squaring both sides allows isolating VV.
4
Substitute the given numerical values and calculate VV.
\(V = \frac{(6.6 \times 10^{-34})^2}{2(9.0 \times 10^{-31})(1.6 \times 10^{-19})(1.1 \times 10^{-10})^2} = 125\text{ V}\)
Performing the algebraic substitution yields the final potential.

Key Concept

de Broglie wavelength of an electron accelerated through a potential difference
Estimated Time:1m 30s
Question 12854Question

An alternating voltage source described by V(t)=2102sin(100πt) VV(t) = 210\sqrt{2}\sin(100\pi t)\ \text{V} is connected in series with a 40 Ω40\ \Omega resistor, an inductor of inductive reactance 100 Ω100\ \Omega, and a capacitor of capacitive reactance 70 Ω70\ \Omega. What is the root-mean-square (RMS) current flowing through the circuit?

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Answer: 4.2 A4.2\ \text{A}

Answer

The root-mean-square (RMS) current flowing through the circuit is 4.2 A4.2\ \text{A}.
The peak voltage is V0=2102 VV_0 = 210\sqrt{2}\ \text{V}, giving an RMS voltage of Vrms=V02=210 VV_{\text{rms}} = \frac{V_0}{\sqrt{2}} = 210\ \text{V}. The impedance of the series RLC circuit is calculated by Z=R2+(XLXC)2=402+(10070)2=50 ΩZ = \sqrt{R^2 + (X_L - X_C)^2} = \sqrt{40^2 + (100 - 70)^2} = 50\ \Omega. Therefore, the RMS current is Irms=VrmsZ=21050=4.2 AI_{\text{rms}} = \frac{V_{\text{rms}}}{Z} = \frac{210}{50} = 4.2\ \text{A}.

Step-by-Step Solution

1
Determine the RMS voltage from the voltage equation
Vrms=210 VV_{\text{rms}} = 210\ \text{V}
The standard equation for AC voltage is V(t)=V0sin(ωt)V(t) = V_0 \sin(\omega t), where V0=2102 VV_0 = 210\sqrt{2}\ \text{V}. The RMS voltage is Vrms=V02=210 VV_{\text{rms}} = \frac{V_0}{\sqrt{2}} = 210\ \text{V}.
2
Calculate the total impedance of the series RLC circuit
Z=50 ΩZ = 50\ \Omega
Impedance is determined using phasor addition: Z=R2+(XLXC)2=402+(10070)2=1600+900=2500=50 ΩZ = \sqrt{R^2 + (X_L - X_C)^2} = \sqrt{40^2 + (100 - 70)^2} = \sqrt{1600 + 900} = \sqrt{2500} = 50\ \Omega.
3
Calculate the RMS current using Ohm's law for AC circuits
Irms=4.2 AI_{\text{rms}} = 4.2\ \text{A}
Irms=VrmsZ=210 V50 Ω=4.2 AI_{\text{rms}} = \frac{V_{\text{rms}}}{Z} = \frac{210\ \text{V}}{50\ \Omega} = 4.2\ \text{A}.

Key Concept

Impedance and RMS current calculation in series RLC alternating current circuits
Estimated Time:2m 0s
Question 12855Question

A nation's economic records for a given fiscal year provide the following national income figures:

- Gross Domestic Product (GDP\text{GDP}): N5,400 million\text{N}5,400\text{ million}
- Income earned by domestic citizens working abroad: N450 million\text{N}450\text{ million}
- Income earned by foreign nationals operating domestically: N600 million\text{N}600\text{ million}
- Capital Consumption Allowance (CCA\text{CCA}): N380 million\text{N}380\text{ million}

Calculate the Net National Product (NNP\text{NNP}) of the country in millions of Naira.

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Answer: 4870

Answer

The Net National Product (NNP) of the country is N4,870 million.
Net National Product (NNP) is obtained by adding Net Factor Income from Abroad (NFIA) to Gross Domestic Product (GDP) to get Gross National Product (GNP), and then subtracting Capital Consumption Allowance (CCA). Here, NFIA = N450 million - N600 million = -N150 million. Thus, GNP = N5,400 million - N150 million = N5,250 million. Finally, NNP = N5,250 million - N380 million = N4,870 million.

Step-by-Step Solution

1
Calculate Net Factor Income from Abroad (NFIA)
NFIA = N450 million - N600 million = -N150 million
NFIA measures the net flow of factor payments between domestic citizens abroad and foreign residents domestically.
2
Calculate Gross National Product (GNP)
GNP = N5,400 million + (-N150 million) = N5,250 million
GNP adjusts GDP for net factor receipts from abroad.
3
Calculate Net National Product (NNP)
NNP = N5,250 million - N380 million = N4,870 million
NNP reflects the net output available to an economy after accounting for capital depreciation.

Key Concept

Basic National Income Aggregates (GDP, GNP, NNP, NDP)
Question 12856Question

Match each specific electronic structure scenario or electron assignment with the corresponding quantum principle or thermodynamic factor that governs it.

Click a left item, then click its matching right item

Items

The ground-state electron configuration of copper being [Ar]3d104s1[Ar]3d^{10}4s^1 rather than [Ar]3d94s2[Ar]3d^9 4s^2
The impossibility of two electrons in an atom having the identical quantum set (2,1,1,+12)(2, 1, -1, +\frac{1}{2})
Nitrogen placing one electron in each of the 2px2p_x, 2py2p_y, and 2pz2p_z orbitals with parallel spins
Filling the 4s4s subshell (n+l=4n+l=4) before commencing the filling of the 3d3d subshell (n+l=5n+l=5)

Matches

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Answer

The correct pairings match copper's anomalous configuration to full-subshell exchange energy stability, identical quantum set restriction to the Pauli exclusion principle, unpaired degenerate orbital filling in nitrogen to Hund's rule, and 4s4s filling prior to 3d3d to the Aufbau (n+l)(n+l) principle.
Each scenario directly aligns with its foundational quantum principle: copper's ground-state configuration ([Ar]3d104s1[Ar]3d^{10}4s^1) is stabilized by high exchange energy of the full dd-subshell; identical quantum numbers are forbidden by the Pauli exclusion principle; single filling of degenerate 2p2p orbitals in nitrogen obeys Hund's rule of maximum multiplicity; and subshell filling order (4s4s before 3d3d) is governed by the Aufbau (n+l)(n+l) rule.

Step-by-Step Solution

1
Analyze the copper configuration anomaly ([Ar]3d104s1[Ar]3d^{10}4s^1).
Identified as a deviation due to exchange energy stabilization of a completely filled dd subshell.
Completely filled subshells provide enhanced stability via maximum exchange interactions and spherical symmetry.
2
Examine the prohibition of identical four-quantum-number sets (n,l,ml,ms)(n, l, m_l, m_s).
Identified as a direct statement of the Pauli exclusion principle.
Two electrons in an orbital must have opposite spin quantum numbers (+12+\frac{1}{2} and 12-\frac{1}{2}).
3
Evaluate nitrogen's 2p32p^3 configuration (2px12py12pz12p_x^1 2p_y^1 2p_z^1).
Identified as an application of Hund's rule of maximum multiplicity.
Electrons occupy degenerate subshell orbitals singly with parallel spins to minimize inter-electronic coulomb repulsion.
4
Assess the sequence of filling 4s4s prior to 3d3d.
Identified as following the Aufbau principle via the (n+l)(n+l) rule.
For 4s4s, n+l=4+0=4n+l = 4+0 = 4; for 3d3d, n+l=3+2=5n+l = 3+2 = 5. Lower (n+l)(n+l) subshells fill first.

Key Concept

Quantum Rules, Subshell Energies, and Electronic Configuration Anomalies
Question 12857Question

Duchenne muscular dystrophy is an X-linked recessive genetic condition in humans. If a female carrier (XDXdX^D X^d) marries a male affected by the condition (XdYX^d Y), what is the probability that their first child will be an affected female?

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Answer: 25%25\%

Answer

The probability that their first child will be an affected female is 25% (or 1/4).
The correct answer is 25%. A cross between a carrier mother (XDXdX^D X^d) and an affected father (XdYX^d Y) yields four equally likely offspring genotypes: XDXdX^D X^d (carrier female), XdXdX^d X^d (affected female), XDYX^D Y (unaffected male), and XdYX^d Y (affected male). Since only 1 of the 4 possible outcomes represents an affected female (XdXdX^d X^d), the probability is 1 out of 4, or 25%.

Step-by-Step Solution

1
Determine the parental genotypes
Mother = XDXdX^D X^d (carrier female); Father = XdYX^d Y (affected male).
Duchenne muscular dystrophy is an X-linked recessive disorder, so the father must carry the recessive allele on his single X chromosome.
2
Construct a Punnett square for the cross
Gametes: Mother produces XDX^D and XdX^d; Father produces XdX^d and YY.
Offspring Genotypes: XDXdX^D X^d (carrier female), XdXdX^d X^d (affected female), XDYX^D Y (unaffected male), XdYX^d Y (affected male).
Each of the 4 combinations is equally likely (25% chance each).
3
Identify the target phenotype among all possible offspring
The target genotype for an affected female is XdXdX^d X^d, which accounts for 1 out of 4 possible total outcomes.
Probability = 14=25%\frac{1}{4} = 25\%.

Key Concept

X-linked recessive inheritance patterns and probability calculations across total offspring versus sex-specific subsets.
Question 12858Question

An α\alpha-particle has a mass approximately 44 times that of a proton and carries 22 times the elementary charge of a proton. If both particles are accelerated from rest through the same potential difference VV, what is the ratio of the de Broglie wavelength of the α\alpha-particle to that of the proton?

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Answer: 1:221 : 2\sqrt{2}

Answer

The ratio of the de Broglie wavelength of the α\alpha-particle to that of the proton is 1:221 : 2\sqrt{2}.
The de Broglie wavelength of a particle accelerated by a potential difference VV is given by λ=h2mqV\lambda = \frac{h}{\sqrt{2mqV}}. Taking the ratio of wavelengths yields λαλp=mpqpmαqα=mpe(4mp)(2e)=18=122\frac{\lambda_\alpha}{\lambda_p} = \sqrt{\frac{m_p q_p}{m_\alpha q_\alpha}} = \sqrt{\frac{m_p e}{(4m_p)(2e)}} = \frac{1}{\sqrt{8}} = \frac{1}{2\sqrt{2}}.

Step-by-Step Solution

1
Relate de Broglie wavelength to accelerating potential
λ=hp=h2mEk=h2mqV\lambda = \frac{h}{p} = \frac{h}{\sqrt{2mE_k}} = \frac{h}{\sqrt{2mqV}}
The kinetic energy gained by a charged particle accelerated through a potential difference VV is Ek=qVE_k = qV.
2
Express wavelengths for both particles
λp=h2mpeV\lambda_p = \frac{h}{\sqrt{2 m_p e V}} and λα=h2mαqαV\lambda_\alpha = \frac{h}{\sqrt{2 m_\alpha q_\alpha V}}
Setting up the parametric expressions for proton (mp,em_p, e) and α\alpha-particle (mα,qαm_\alpha, q_\alpha).
3
Substitute relative values mα=4mpm_\alpha = 4m_p and qα=2eq_\alpha = 2e
λα=h2(4mp)(2e)V=h16mpeV=h4mpeV\lambda_\alpha = \frac{h}{\sqrt{2(4m_p)(2e)V}} = \frac{h}{\sqrt{16 m_p e V}} = \frac{h}{4\sqrt{m_p e V}}
Using the given relationships between mass and charge of the two particles.
4
Calculate the ratio λαλp\frac{\lambda_\alpha}{\lambda_p}
λαλp=h4mpeVh2mpeV=24=122\frac{\lambda_\alpha}{\lambda_p} = \frac{\frac{h}{4\sqrt{m_p e V}}}{\frac{h}{\sqrt{2 m_p e V}}} = \frac{\sqrt{2}}{4} = \frac{1}{2\sqrt{2}}
Simplifying the fractional ratio of wavelengths.

Key Concept

de Broglie Wavelength of Charged Particles Accelerated in Electric Fields
Question 12859Question

A sample of a radioactive isotope used in medical imaging has an initial activity of 320 MBq320\text{ MBq}. If its activity decreases to 20 MBq20\text{ MBq} after an elapsed time of 15 hours15\text{ hours}, what is the half-life of the isotope in hours?

Show answer & explanation

Answer: 3.75

Answer

The half-life of the radioactive isotope is 3.75 hours3.75\text{ hours}.
The initial activity of 320 MBq320\text{ MBq} drops to 20 MBq20\text{ MBq}, which is a reduction to 20320=116\frac{20}{320} = \frac{1}{16} of its original value. Since 116=(12)4\frac{1}{16} = \left(\frac{1}{2}\right)^4, exactly 4 half-lives have elapsed over the period of 15 hours15\text{ hours}. Therefore, one half-life is 15 hours4=3.75 hours\frac{15\text{ hours}}{4} = 3.75\text{ hours}.

Step-by-Step Solution

1
Calculate the fraction of initial activity remaining
Fraction remaining = 20 MBq320 MBq=116\frac{20\text{ MBq}}{320\text{ MBq}} = \frac{1}{16}
The ratio of current activity to initial activity determines the fraction of un-decayed nuclei remaining.
2
Determine the number of half-lives (nn) that have elapsed
n=4n = 4 half-lives, since (12)4=116\left(\frac{1}{2}\right)^4 = \frac{1}{16}
Each half-life reduces the remaining sample activity by half.
3
Calculate the half-life duration (T1/2T_{1/2})
T1/2=tn=15 hours4=3.75 hoursT_{1/2} = \frac{t}{n} = \frac{15\text{ hours}}{4} = 3.75\text{ hours}
Dividing total elapsed time by the number of half-lives gives the duration of one half-life.

Key Concept

Radioactive Decay Law and relationship between remaining activity fraction, number of half-lives, and total elapsed time.
Question 12860Question

Match each physical electromagnetic configuration listed under Column I with its corresponding net magnetic force or motion characteristic listed under Column II.

Click a left item, then click its matching right item

Items

A charged particle projected parallel to the lines of a uniform magnetic field
Two long, straight parallel conductors carrying electric currents in opposite directions
A current-carrying rectangular wire coil positioned with its plane parallel to a uniform magnetic field
A charged particle injected perpendicularly into a uniform magnetic field

Matches

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Answer

1. Charged particle moving parallel to magnetic field lines \rightarrow Experiences zero magnetic force (F=0F = 0) and maintains its initial linear trajectory.
2. Parallel conductors carrying opposite currents \rightarrow Experience a mutually repulsive force per unit length given by FL=μ0I1I22πd\frac{F}{L} = \frac{\mu_0 I_1 I_2}{2\pi d}.
3. Current-carrying rectangular coil parallel to magnetic field \rightarrow Experiences maximum net magnetic torque (τ=NIAB\tau = N I A B) while net translational force is zero.
4. Charged particle injected perpendicularly into magnetic field \rightarrow Follows a uniform circular path due to a constant magnetic centripetal force (F=qvBF = qvB).
Each electromagnetic system is correctly paired based on the vector cross-product rules governing magnetic force (F=q(v×B)F = q(\mathbf{v} \times \mathbf{B}) and F=I(L×B)F = I(\mathbf{L} \times \mathbf{B})). Parallel motion produces zero force due to zero angle; opposite currents repel per unit length according to Ampère's law; a parallel loop experiences maximal couple/torque without linear displacement; and perpendicular particle velocity results in a constant centripetal deflection into circular motion.

Step-by-Step Solution

1
Analyze the angle θ\theta between velocity and magnetic field for a parallel moving charge
Since velocity is parallel to the field, θ=0\theta = 0^\circ. The magnetic Lorentz force formula F=qvBsinθF = qvB\sin\theta yields F=0F = 0, meaning no deflection occurs.
Magnetic forces require a non-zero perpendicular component of motion relative to the magnetic field direction.
2
Determine the interaction force between parallel conductors with opposite currents
By applying the magnetic field rule for long straight conductors and Fleming's left-hand rule for the resulting force, currents flowing in opposite directions repel each other with force per unit length FL=μ0I1I22πd\frac{F}{L} = \frac{\mu_0 I_1 I_2}{2\pi d}.
Opposite current directions generate magnetic field lines between the wires that reinforce each other, creating a high-density magnetic field region that pushes the conductors apart.
3
Evaluate forces and torque on a rectangular coil aligned parallel to magnetic field lines
The forces on opposite arms are equal in magnitude and opposite in direction, canceling out net linear translation (Fnet=0F_{\text{net}} = 0). However, they act along different lines of action, producing a maximum torque τ=NIABcos0=NIAB\tau = N I A B \cos 0^\circ = N I A B.
Maximum torque occurs when the plane of the coil is parallel to the field because the lever arm for the magnetic forces on the side conductors is at its maximum length.
4
Evaluate the trajectory of a charged particle entering perpendicularly into a magnetic field
At θ=90\theta = 90^\circ, sin90=1\sin 90^\circ = 1, giving a constant magnetic force F=qvBF = qvB. Because vector force is perpendicular to velocity at every instant, it changes only the direction of velocity, driving the particle into a circular orbit of radius r=mvqBr = \frac{mv}{qB}.
A constant magnitude force acting perpendicular to the instantaneous velocity vectors fulfills the exact condition for centripetal acceleration.

Key Concept

Magnetic forces on moving charges and current-carrying conductors under specific geometric alignments and current configurations
Estimated Time:3m 0s
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