Experimental Design and Scientific Method

201 questions

Question 61Question

A student proposes the following hypothesis regarding the thermal stability of Group 2 metal carbonates:

*Hypothesis*: The decomposition temperature of a Group 2 metal carbonate is directly proportional to the charge density of its metal cation. Because charge density decreases as ionic radius increases, metal carbonates with larger metal cations will decompose at lower temperatures.

A chemist conducts an experiment to test this hypothesis by measuring the decomposition temperature (TdT_d, the temperature at which the carbonate decomposes into a metal oxide and carbon dioxide) of four Group 2 metal carbonates. The results are shown in Table 1.

### Table 1
Metal CarbonateMetal CationCation Ionic Radius (pm\text{pm})Decomposition Temperature (C^\circ\text{C})
MgCO3\text{MgCO}_3Mg2+\text{Mg}^{2+}72350
CaCO3\text{CaCO}_3Ca2+\text{Ca}^{2+}100825
SrCO3\text{SrCO}_3Sr2+\text{Sr}^{2+}1181,100
BaCO3\text{BaCO}_3Ba2+\text{Ba}^{2+}1351,360

Based on Table 1, is the student's hypothesis supported by the experimental results, and how should the hypothesis be modified?

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Answer: No; the hypothesis should be modified to state that as the ionic radius of the metal cation increases, the decomposition temperature increases.

Answer

The student's hypothesis is not supported because the experimental data show that as the ionic radius of the metal cation increases, the decomposition temperature increases. Therefore, the hypothesis should be modified to state that as the ionic radius of the metal cation increases, the decomposition temperature increases.
The experimental results show that as the ionic radius increases, the decomposition temperature increases. This trend is the opposite of the student's prediction that larger cations would decompose at lower temperatures. Thus, the hypothesis is not supported and must be modified to state that as the ionic radius of the metal cation increases, the decomposition temperature increases.

Step-by-Step Solution

1
Determine the prediction made by the student's hypothesis.
The student predicted that since charge density decreases as ionic radius increases, larger metal cations would lead to lower decomposition temperatures (an inverse relationship between ionic radius and decomposition temperature).
To evaluate a hypothesis, we must first clearly define the relationship it predicts.
2
Analyze the experimental data in Table 1 to identify the actual trend.
As the ionic radius of the cation increases from 72 pm72\text{ pm} (Mg2+\text{Mg}^{2+}) to 135 pm135\text{ pm} (Ba2+\text{Ba}^{2+}), the decomposition temperature increases from 350 C350\ ^\circ\text{C} to 1,360 C1,360\ ^\circ\text{C} (a direct relationship).
This establishes the empirical relationship demonstrated by the experiment.
3
Compare the predicted trend with the observed trend.
The observed direct relationship is the opposite of the predicted inverse relationship, meaning the hypothesis is not supported.
Comparing predictions with actual data determines whether the hypothesis is supported or refuted.
4
Formulate the correct modification to the hypothesis.
The hypothesis should be modified to state that as the ionic radius of the metal cation increases, the decomposition temperature increases.
Modifying a refuted hypothesis requires aligning it with the experimental evidence.

Key Concept

Evaluating and modifying a hypothesis based on empirical data trends
Question 62Question

Suppose a scientist wants to modify an electroplating procedure to isolate the specific effect of temperature on the deposition rate of copper and determine the activation energy of the reaction. The scientist must ensure that concentration depletion and current fluctuations do not confound the results. Arrange the following steps in the correct chronological order to design and execute this modified follow-up experiment.

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Answer

The correct chronological sequence begins with preparing the high-volume electrolyte bath to maintain constant concentration. Next, preliminary trials are run to determine the optimal constant current. Once the current is established, the temperature-controlled trials are executed. After the trials, the deposited mass is measured to calculate rates. Finally, these rates are plotted against the reciprocal of absolute temperature to calculate the activation energy.
The correct sequence begins with preparing the high-volume electrolyte bath to ensure concentration remains constant. Next, preliminary trials must be run to determine the optimal current. Once the current is established, the temperature-controlled trials are executed. After completing the trials, the mass of deposited copper is measured to calculate rates. Finally, these rates are plotted to calculate activation energy.

Step-by-Step Solution

1
Prepare the constant concentration electrolyte bath.
Maintains a stable chemical environment.
This must be done first so that all subsequent trials, including preliminary calibration, use the same electrolyte concentration.
2
Run preliminary trials to select the operating current.
Determines the optimal constant current value.
A constant current must be selected prior to running the main experimental trials to properly control this variable.
3
Execute the temperature-controlled trials.
Generates copper deposition at different temperatures.
This step uses the selected current and prepared bath to collect raw data across the independent temperature variable.
4
Measure mass and calculate deposition rates.
Obtains the rate of deposition for each temperature.
The rate data is the dependent variable required for the final activation energy calculation.
5
Construct an Arrhenius plot.
Determines the activation energy.
This final analytical step uses the rates calculated from the trials to perform the mathematical analysis.

Key Concept

Isolating independent variables and controlling confounding factors in a multi-step sequence for follow-up experimental design.
Estimated Time:3m 0s
Question 63Question

A student wants to investigate how the volume of water affects the time it takes for the water to boil. In Trial 1, the student heats 100 mL100\text{ mL} of water in a glass beaker on a hot plate set to High (Level 1010). In Trial 2, the student heats 200 mL200\text{ mL} of water in an identical glass beaker on a different hot plate set to Medium (Level 55). Which of the following is an uncontrolled variable in this experiment that prevents the student from drawing a valid conclusion?

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Answer: The heat setting of the hot plates

Answer

The heat setting of the hot plates
To determine how water volume affects boiling time, all other variables, such as the heat setting of the hot plates, must be kept constant. Because the hot plates were set to different levels (High in Trial 1 and Medium in Trial 2), the heat setting is an uncontrolled variable that confounds the results.

Step-by-Step Solution

1
Identify the independent variable (what is intentionally changed to test its effect) and the dependent variable (what is measured).
The independent variable is the volume of water (100 mL100\text{ mL} vs. 200 mL200\text{ mL}). The dependent variable is the boiling time.
This establishes the core relationship the student intends to study.
2
Examine the experimental procedure for any variables other than the independent variable that changed between trials.
The heat setting changed between trials (Level 1010 in Trial 1, Level 55 in Trial 2).
Any variable that changes alongside the independent variable acts as a confounding variable, making it impossible to determine which factor caused the observed change in the dependent variable.
3
Identify the variable that was kept constant to confirm it is not confounding.
The beaker material was kept constant (both were identical glass beakers).
Controlled variables do not introduce experimental error or confound the results.

Key Concept

Identifying Sources of Error and Confounding Variables
Estimated Time:45s
Question 64Question

To investigate how reactant surface area affects the rate of a chemical reaction, students performed three trials. In each trial, 5.0 g5.0\text{ g} of calcium carbonate (CaCO3CaCO_3) was added to 100 mL100\text{ mL} of 1.0 M1.0\text{ M} hydrochloric acid (HClHCl) at an initial temperature of 20.0C20.0^\circ\text{C} in an uninsulated beaker. The reaction is represented by the following equation:

CaCO3(s)+2HCl(aq)CaCl2(aq)+CO2(g)+H2O(l)+ΔHCaCO_3(s) + 2HCl(aq) \rightarrow CaCl_2(aq) + CO_2(g) + H_2O(l) + \Delta H

The students recorded the particle size of the CaCO3CaCO_3, the time required for the reaction to go to completion, and the maximum temperature reached during each trial. The results are shown in the table below:

TrialCaCO3CaCO_3 Particle SizeTime to Completion (s)Maximum Temperature Reached (C^\circ\text{C})
11Large chunks24024021.521.5
22Small chips12012026.226.2
33Fine powder303038.838.8

Which of the following statements best explains how the maximum temperature reached acts as a confounding variable that prevents the students from drawing a valid conclusion about the effect of particle size on the reaction rate?

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Answer: The unequal temperature rise among the trials increases the average kinetic energy of the reactants in the faster trials, meaning the difference in reaction times cannot be attributed solely to the difference in particle size.

Answer

The correct answer explains that the unequal temperature rise among the trials increases the average kinetic energy of the reactants in the faster trials, meaning the difference in reaction times cannot be attributed solely to the difference in particle size.
The correct answer explains that the unequal temperature rise among the trials increases the average kinetic energy of the reactants in the faster trials, meaning the difference in reaction times cannot be attributed solely to the difference in particle size. Since temperature is known to affect reaction rate, the fact that the temperature rose much higher in the fine powder trial than in the large chunks trial means that both temperature and surface area changed simultaneously, confounding the results.

Step-by-Step Solution

1
Identify the independent, dependent, and controlled variables in the setup.
The independent variable is the particle size of calcium carbonate, and the dependent variable is the time to completion. The controlled variables include the mass of calcium carbonate, the volume and concentration of hydrochloric acid, and the initial temperature.
Establishing the variable roles is necessary to detect any extraneous variables that are not properly controlled.
2
Analyze the maximum temperature data across the trials.
The maximum temperature rose from 21.5C21.5^\circ\text{C} in Trial 1 (slowest) to 38.8C38.8^\circ\text{C} in Trial 3 (fastest).
This temperature difference shows that a variable influencing reaction rate (temperature) was not constant across trials during the reaction.
3
Determine how this temperature variation affects the interpretation of the results.
Higher temperatures increase the kinetic energy of reactants, which accelerates the reaction. Therefore, the faster rate in Trial 3 is caused by both the smaller particle size and the higher temperature.
This shows that temperature acts as a confounding variable, making it impossible to isolate the effect of particle size alone.

Key Concept

A confounding variable is an uncontrolled factor that varies systematically with the independent variable, making it impossible to isolate the true cause of the observed changes in the dependent variable.
Estimated Time:2m 0s
Question 65Question

In scientific investigations, identifying potential sources of error and confounding variables is critical to ensuring the validity of experimental results. Match each experimental scenario to the primary uncontrolled confounding variable that threatens the validity of its results.

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Items

Testing how fertilizer amount affects plant growth by placing fertilized plants in a sunny window and unfertilized plants in a dark closet.
Measuring the boiling point of salt water across multiple trials, where tap water is used in some trials and distilled water is used in others.
Comparing how fast ice melts on different surfaces, where some trials are conducted in an air-conditioned room and others are conducted outdoors.

Matches

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Answer

The plant growth experiment matches with differences in sunlight exposure; the salt water boiling experiment matches with variations in water purity; and the ice melting experiment matches with differences in ambient temperature.
Each correct pairing links an experimental setup that fails to keep a background condition constant with the specific environmental or chemical factor that was allowed to vary.

Step-by-Step Solution

1
Analyze the plant growth experiment to identify the variables.
The independent variable is fertilizer amount, but the groups also differ in location (sunny window vs. dark closet), which introduces sunlight as an uncontrolled variable.
To ensure a fair test, all factors other than the fertilizer amount must be kept constant.
2
Analyze the salt water boiling point experiment to identify the variables.
The trials use different types of water (tap vs. distilled), introducing chemical impurities as a confounding variable.
Impurities in solvent can alter boiling point, confounding the effect of the added salt.
3
Analyze the ice melting experiment to identify the variables.
The trials are performed in different locations with different ambient temperatures (indoor air-conditioning vs. outdoors), introducing temperature as an uncontrolled variable.
Ambient temperature directly affects the rate of heat transfer and ice melting.

Key Concept

Identifying Sources of Error and Confounding Variables
Question 66Question

A student conducted an experiment to investigate the effect of light wavelength on the rate of photosynthesis in *Elodea* plants. The student formulated the following hypothesis:

*Hypothesis:* The rate of photosynthesis, as measured by the volume of oxygen (O2O_2) gas produced per hour, increases continuously as the wavelength of light increases from 400 nm400\text{ nm} to 700 nm700\text{ nm}.

The student exposed identical *Elodea* plants to different wavelengths of light for 1 hour each, keeping all other environmental variables constant. The results are shown in the table below:

WavelengthVolume of O2O_2 produced
400 nm400\text{ nm}1.2 mL1.2\text{ mL}
450 nm450\text{ nm}4.5 mL4.5\text{ mL}
550 nm550\text{ nm}0.3 mL0.3\text{ mL}
650 nm650\text{ nm}5.8 mL5.8\text{ mL}
700 nm700\text{ nm}1.0 mL1.0\text{ mL}

Based on the results of the experiment, does the data support the student's hypothesis, and how should the hypothesis be modified?

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Answer: No; the rate of photosynthesis does not increase continuously, so the hypothesis should be modified to state that photosynthesis peaks under blue (450 nm450\text{ nm}) and red (650 nm650\text{ nm}) light.

Answer

No; the rate of photosynthesis does not increase continuously, so the hypothesis should be modified to state that photosynthesis peaks under blue (450 nm450\text{ nm}) and red (650 nm650\text{ nm}) light.
The correct answer is correct because the experimental results show that oxygen production does not increase continuously. Instead, it rises and falls, reaching local maxima at 450 nm450\text{ nm} and 650 nm650\text{ nm}, and a minimum at 550 nm550\text{ nm}. Therefore, the hypothesis is unsupported and must be modified to state that photosynthesis is most efficient (peaks) at specific wavelengths corresponding to blue and red light.

Step-by-Step Solution

1
Analyze the student's hypothesis.
The hypothesis predicts a continuous, monotonic increase in oxygen production as wavelength increases from 400 nm400\text{ nm} to 700 nm700\text{ nm}.
Understanding the prediction is necessary to evaluate it against the experimental data.
2
Examine the trend in the data table.
The volume of oxygen increases from 1.2 mL1.2\text{ mL} (at 400 nm400\text{ nm}) to 4.5 mL4.5\text{ mL} (at 450 nm450\text{ nm}), drops to 0.3 mL0.3\text{ mL} (at 550 nm550\text{ nm}), increases to 5.8 mL5.8\text{ mL} (at 650 nm650\text{ nm}), and drops again to 1.0 mL1.0\text{ mL} (at 700 nm700\text{ nm}).
This determines whether the actual rate of photosynthesis increases continuously.
3
Compare the data to the hypothesis and determine the appropriate modification.
Because the trend shows peaks at 450 nm450\text{ nm} and 650 nm650\text{ nm} rather than a continuous increase, the hypothesis is not supported and should be modified to describe these dual peaks.
Formulating a modified hypothesis must accurately represent the observed experimental results.

Key Concept

Formulating and Modifying Hypotheses
Estimated Time:1m 30s
Question 67Question

A student conducted an experiment to measure the distance a 50 g50\text{ g} toy car traveled along a flat floor after rolling down a 1 m1\text{ m} wooden ramp set at an angle of 3030^\circ. The student performed 3 trials using the same car and ramp. Suppose the student wants to design a follow-up experiment to determine how the mass of the car affects the distance it travels. Which of the following modifications to the procedure should the student make to test this relationship?

Show answer & explanation

Answer: Test toy cars of different masses while keeping the ramp angle, ramp length, and ramp material the same.

Answer

Test toy cars of different masses while keeping the ramp angle, ramp length, and ramp material the same.
The correct answer proposes varying only the mass of the toy car while keeping all other parameters—such as ramp angle, length, and material—constant. This isolates the car's mass as the single independent variable, which is necessary to determine its direct effect on the distance traveled.

Step-by-Step Solution

1
Identify the independent variable that needs to be tested in the follow-up experiment.
The independent variable is the mass of the toy car.
The student wants to determine the specific effect of the car's mass on the distance it travels.
2
Identify the controlled variables that must remain constant.
The ramp angle (3030^\circ), ramp length (1 m1\text{ m}), and ramp material (wooden) must remain unchanged across trials.
To ensure a fair test, all variables except the one being tested must be controlled.
3
Evaluate the choices to find the one that alters only the mass of the car while keeping the ramp conditions constant.
Testing cars of different masses with the same ramp setup is the correct design.
This isolates the mass of the car as the single independent variable affecting the dependent variable (distance traveled).

Key Concept

To isolate the effect of a new independent variable in a follow-up experiment, only that variable should be changed, while all other variables from the original design must be controlled.
Question 68Question

A student group is designing various laboratory investigations. During their planning phase, they identify potential sources of error and confounding variables in their experimental setups. Match each described experimental procedure with the primary source of error or confounding variable that threatens its validity.

Click a left item, then click its matching right item

Items

Testing the effect of temperature on the rate of yeast respiration by placing the 30C30^\circ\text{C} trials in a dark incubator and the 20C20^\circ\text{C} trials on a brightly lit window sill.
Comparing the transpirational water loss of two plant species by planting Species XX in porous clay pots and Species YY in non-porous plastic pots, while maintaining identical soil volume and watering schedules.
Determining how pHpH affects enzyme activity by using a different chemical buffer system for each pHpH level, where some buffer salts can independently bind to and inhibit the enzyme's active site.
Investigating the impact of wind speed on soil evaporation rates by conducting trials at high wind speeds in the morning and trials at zero wind speed at night in a greenhouse where the ambient relative humidity fluctuates daily.

Matches

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Answer

Testing yeast respiration temperature effects matches with light exposure confounding; comparing plant transpiration in clay vs. plastic pots matches with container permeability differences; determining pH effects on enzymes using different buffers matches with chemical interference from buffer salts; investigating wind speed effects at different times of day matches with fluctuating ambient humidity.
Each experimental procedure is correctly matched to its confounding variable: testing yeast at different temperatures under different light conditions introduces light as an uncontrolled variable; using different pot materials (clay vs. plastic) introduces container permeability as a confounder; using different buffer compounds introduces chemical interference; and conducting evaporation trials at different times of day introduces fluctuating relative humidity as an uncontrolled factor.

Step-by-Step Solution

1
Analyze the yeast respiration procedure.
The yeast respiration experiment varies both temperature (30C30^\circ\text{C} vs. 20C20^\circ\text{C}) and light exposure (dark incubator vs. lit window). This introduces light as a confounding factor.
Identifying that multiple independent variables are changing at once highlights the source of error.
2
Analyze the plant transpiration comparison.
The plant transpiration experiment uses porous clay pots for one species and non-porous plastic pots for another. Clay pots allow water evaporation through their walls, introducing container permeability as an uncontrolled variable.
Isolating structural differences in experimental containers reveals the confounding factor.
3
Analyze the enzyme pH activity experiment.
Using different buffer formulations to vary pH introduces different chemical salts. If these salts bind to the enzyme, the observed activity changes may stem from chemical interference rather than pH.
Recognizing that changing buffer types introduces new chemical species explains the confounding effect.
4
Analyze the soil evaporation and wind speed experiment.
Running wind speed trials at different times of day (morning vs. night) in an environment with fluctuating relative humidity introduces humidity as an uncontrolled variable.
Identifying temporal differences in testing conditions reveals the environmental confounding variable.

Key Concept

Identifying uncontrolled variables and confounding factors that prevent researchers from drawing valid conclusions about the relationship between the independent and dependent variables.
Question 69Question

An investigator designed an experiment to determine how pH affects the rate of starch hydrolysis by the enzyme amylase. The investigator prepared four test tubes, each containing an identical concentration of starch and amylase at a specific pH. To establish and maintain each pH level, the investigator used different buffer systems, as summarized in the table below:

TubepHBuffer System ComponentsRate of Starch Hydrolysis (mg/min\text{mg/min})
14.04.0Citric acid / Sodium citrate0.20.2
26.06.0Phosphate buffer / Sodium chloride1.81.8
38.08.0Tris-HCl / Potassium chloride1.21.2
410.010.0Carbonate / Bicarbonate0.10.1

Given that amylase activity is stimulated by the presence of chloride (ClCl^-) ions, which of the following statements best identifies the confounding variable in this experiment and its potential impact on the results?

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Answer: The presence of chloride ions in the buffers for Tube 2 and Tube 3, which may artificially elevate the measured hydrolysis rates at pH 6.0 and pH 8.0.

Answer

The presence of chloride ions in the buffers for Tube 2 and Tube 3, which may artificially elevate the measured hydrolysis rates at pH 6.0 and pH 8.0.
The correct answer identifies chloride ions as the confounding variable. Because chloride ions stimulate amylase activity and are only present in the buffer systems of two of the treatment groups (Tubes 2 and 3), the rates of hydrolysis at pH 6.06.0 and 8.08.0 are artificially elevated, preventing an accurate comparison of the effect of pH alone.

Step-by-Step Solution

1
Identify the intended independent variable and the dependent variable.
The independent variable is pH (varying from 4.04.0 to 10.010.0), and the dependent variable is the rate of starch hydrolysis.
This establishes what the experiment is designed to measure and helps isolate any unintended variables.
2
Analyze the buffer components for each tube to identify any differences that do not correlate with pH.
Tube 2 contains sodium chloride (supplying ClCl^- ions) and Tube 3 contains Tris-HCl and potassium chloride (both supplying ClCl^- ions), while Tube 1 and Tube 4 do not contain chloride components.
Any variable that differs systematically between experimental groups other than the independent variable is a potential confounding variable.
3
Evaluate the impact of the identified difference using the given scientific fact.
Since chloride ions stimulate amylase activity, their presence in Tubes 2 and 3 will increase the reaction rates in those tubes, making the rates at pH 6.06.0 and pH 8.08.0 appear higher due to the chloride ions rather than the pH alone.
This determines how the confounding variable distorts the experimental conclusions.

Key Concept

A confounding variable is an uncontrolled factor that varies systematically with the independent variable, making it impossible to determine whether the observed effects are due to the independent variable or the uncontrolled factor.
Question 70Question

A student proposed the following hypothesis regarding the corrosion of iron:

*Hypothesis*: The mass of rust that forms on an iron nail submerged in a sodium chloride (NaClNaCl) solution for 7 days will increase continuously as the concentration of NaClNaCl in the solution increases from 0% to 10%.

To test this hypothesis, the student submerged identical iron nails in 5 different NaClNaCl solutions for 7 days and recorded the mass of the rust that formed on each nail. The results are shown in the table below:

NaClNaCl concentration (% by mass)Mass of rust formed (mg)
0%1.2
1%3.5
3%5.8
5%4.2
10%2.1

Based on these results, how should the student modify their hypothesis?

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Answer: The student should modify the hypothesis to state that the mass of rust formed increases with NaClNaCl concentration up to approximately 3%, but decreases at higher concentrations.

Answer

The student should modify the hypothesis to state that the mass of rust formed increases with NaClNaCl concentration up to approximately 3%, but decreases at higher concentrations.
The correct option accurately reflects the empirical data, which shows a rise in rust mass up to 3% NaClNaCl concentration followed by a decline at higher concentrations. This requires a modification of the hypothesis from a continuous increase to a peaked relationship.

Step-by-Step Solution

1
Analyze the original hypothesis to identify the predicted trend.
The original hypothesis predicts that the mass of rust will continuously increase as the NaClNaCl concentration increases from 0% to 10%.
This establishes the baseline expectation that must be compared against the actual data.
2
Examine the experimental data in the table to determine the actual trend.
As the concentration increases from 0% to 3%, the mass of rust increases from 1.2 mg to 5.8 mg. However, as the concentration increases further from 3% to 10%, the mass of rust decreases from 5.8 mg to 2.1 mg.
This identifies the pattern of the empirical evidence.
3
Compare the actual trend to the original hypothesis and determine the necessary modification.
Since the mass does not increase continuously but rather peaks at 3% and then decreases, the hypothesis must be modified to reflect this non-linear relationship (increasing up to a point, then decreasing).
This directly matches the learning objective of modifying a hypothesis based on new experimental data.

Key Concept

Formulating and Modifying Hypotheses
Question 71Question

A student wants to modify an experiment measuring sugar solubility in water to determine the effect of higher temperatures (40C40^\circ\text{C}, 60C60^\circ\text{C}, and 80C80^\circ\text{C}) on the mass of dissolved sugar. Arrange the steps of this modified procedure in the correct chronological order from start to finish.

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Answer

The correct order of steps for the modified experiment is first heating the water to a target temperature, next adding sugar until it no longer dissolves, then measuring and recording the mass of the dissolved sugar, and finally repeating these steps for the other temperatures.
The correct order follows a logical experimental procedure for measuring solubility at different temperatures: first, establishing the independent variable (temperature) by heating the water; second, performing the test by adding sugar to saturation; third, measuring the dependent variable (mass of dissolved sugar); and fourth, repeating the process for other levels of the independent variable (other temperatures) while controlling other factors.

Step-by-Step Solution

1
Identify the first step in conducting a solubility test at a specific temperature.
The water sample must be heated to the target temperature (40C40^\circ\text{C}, 60C60^\circ\text{C}, or 80C80^\circ\text{C}) before adding sugar.
Dissolving sugar at the correct starting temperature ensures the solubility measurement is accurate for that temperature.
2
Determine the next physical step in the dissolution process.
Sugar is added incrementally and stirred until the solution becomes saturated.
Saturating the solution is necessary to find the maximum limit of solubility at that temperature.
3
Determine the measurement step that follows saturation.
Measure and record the total mass of sugar dissolved.
Recording the mass at the end of the trial provides the data point for that specific temperature.
4
Determine the final step to complete the study across the full temperature range.
Repeat the entire procedure for the remaining temperatures while keeping the water volume constant.
Testing all temperatures under controlled conditions allows for a valid comparison of solubility trends.

Key Concept

To modify an experiment to test a new range of an independent variable (temperature), one must systematically heat the solvent, dissolve the solute to saturation, measure the mass, and repeat the process under controlled conditions for all remaining values of the independent variable.
Question 72Question

A student conducted an experiment to measure the rate of water loss from a certain plant species under different relative humidity levels. The experimental design is summarized in the table below:

TrialRelative Humidity (%)Temperature (C^\circ\text{C})Plant SpeciesExposure Time (hours)
12025Fern2
24025Fern2
36025Fern2
48025Fern2

Suppose the student wants to perform a follow-up experiment to determine how temperature affects the water loss of this same plant species. Which of the following modifications to the experimental design would best allow the student to isolate the effect of temperature?

Show answer & explanation

Answer: Vary the temperature across trials while keeping the relative humidity, plant species, and exposure time constant.

Answer

Vary the temperature across trials while keeping the relative humidity, plant species, and exposure time constant.
To investigate the effect of a new independent variable (temperature), that variable must be varied while holding all other variables constant. The correct option describes changing the temperature across trials while maintaining constant relative humidity, plant species, and exposure time, which successfully isolates the effect of temperature.

Step-by-Step Solution

1
Identify the goal of the follow-up experiment.
The goal is to determine the specific effect of temperature on water loss (transpiration).
This establishes temperature as the new independent variable.
2
Apply the rule of experimental control.
To isolate the effect of temperature, only temperature should vary, while all other potential independent variables (such as relative humidity, plant species, and exposure time) must remain constant.
Varying multiple factors simultaneously introduces confounding variables, which prevents a clear conclusion about which variable caused the change.
3
Evaluate the choices to find the one that varies only temperature.
The option to vary the temperature while holding relative humidity, plant species, and exposure time constant correctly isolates the variable of interest.
This aligns with proper scientific method and experimental design.

Key Concept

Scientific Control of Variables in Follow-Up Experiments
Question 73Question

An environmental scientist investigated the relationship between water temperature and the concentration of dissolved oxygen (DO) at saturation. The scientist hypothesized that as water temperature increases, the concentration of DO at saturation also increases because higher temperatures increase the solubility of gases in water. To test this hypothesis, the scientist measured the DO concentration at saturation in water samples at five different temperatures. The results are presented in the table below.

Water Temperature (C^\circ\text{C})Dissolved Oxygen Concentration (mg/L\text{mg/L})
5512.812.8
151510.110.1
25258.38.3
35356.96.9
45455.95.9

Based on these results, does the data support the scientist's hypothesis, and how should the hypothesis be revised?

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Answer: No; the revised hypothesis should state that as water temperature increases, the concentration of dissolved oxygen at saturation decreases.

Answer

No; the revised hypothesis should state that as water temperature increases, the concentration of dissolved oxygen at saturation decreases.
The scientist's hypothesis predicted that as temperature increases, the concentration of dissolved oxygen at saturation would also increase. However, the experimental results show that as the temperature increases from 5C5^\circ\text{C} to 45C45^\circ\text{C}, the concentration of dissolved oxygen decreases from 12.8 mg/L12.8\text{ mg/L} to 5.9 mg/L5.9\text{ mg/L}. Because the results show the opposite of the predicted trend, the hypothesis is not supported, and the revised hypothesis must state that as water temperature increases, the concentration of dissolved oxygen at saturation decreases.

Step-by-Step Solution

1
Identify the scientist's original hypothesis and its predicted outcome.
The original hypothesis predicts that an increase in water temperature results in an increase in dissolved oxygen (DO) concentration (a direct relationship).
Establishing the initial prediction allows direct comparison with the actual experimental data.
2
Analyze the trend shown in the experimental data table.
As the temperature increases from 5C5^\circ\text{C} to 45C45^\circ\text{C}, the DO concentration steadily decreases from 12.8 mg/L12.8\text{ mg/L} to 5.9 mg/L5.9\text{ mg/L} (an inverse relationship).
Determining the actual mathematical relationship between the variables reveals if the initial prediction was correct.
3
Determine if the hypothesis is supported and formulate the necessary revision.
The data contradicts the hypothesis, meaning it is not supported (No). The hypothesis must be revised to reflect the inverse trend: as water temperature increases, DO concentration at saturation decreases.
Hypotheses must be modified to align with experimental findings when those findings refute the initial prediction.

Key Concept

Formulating and Modifying Hypotheses
Estimated Time:1m 30s
Question 74Question

A group of students designed several investigations to study how wind speed affects the rate of water evaporation. For each investigation, they set up two trials with different wind speeds. However, each setup introduced a distinct confounding variable or source of error. Match each experimental setup to the primary confounding variable or source of error that threatens its internal validity.

Click a left item, then click its matching right item

Items

Two identical 150 mL150\text{ mL} beakers, each containing 100 mL100\text{ mL} of water, are exposed to different wind speeds. One beaker is positioned directly beneath a laboratory ventilation duct that blows warm air, while the other is placed in a cooler corner of the room.
The evaporation rate under high wind speed is measured using water in a wide-mouthed Petri dish (diameter 10 cm10\text{ cm}), while the rate under low wind speed is measured using water in a narrow beaker (diameter 4 cm4\text{ cm}).
The high-wind trial is performed using a 1.0 M1.0\text{ M} sodium chloride (NaCl\text{NaCl}) aqueous solution, while the low-wind trial is performed using pure, deionized water.
Evaporation rates are compared by measuring the volume of water lost after a 60-minute60\text{-minute} exposure for the high-wind trial, and after a 120-minute120\text{-minute} exposure for the low-wind trial.

Matches

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Answer

The experimental setups match their confounding variables as follows: Setup 1 matches with differences in thermal energy input; Setup 2 matches with differences in exposed liquid-gas interface area; Setup 3 matches with differences in solute concentration; Setup 4 matches with differences in total duration of evaporation.
Each experimental setup introduces a distinct uncontrolled variable: temperature variation corresponds to differences in thermal energy input; diameter differences correspond to exposed liquid-gas interface area; the presence of sodium chloride corresponds to solute concentration; and unequal trial lengths correspond to duration of evaporation.

Step-by-Step Solution

1
Analyze Setup 1, which places one beaker under warm ventilation air and the other in a cooler corner.
This setup introduces temperature differences.
Since temperature directly affects kinetic energy and evaporation rate, this represents differences in thermal energy input.
2
Analyze Setup 2, which uses a 10 cm10\text{ cm} Petri dish and a 4 cm4\text{ cm} beaker.
This setup introduces variations in the surface area of the water exposed to air.
Water evaporates only from its surface, so changing the diameter alters the exposed liquid-gas interface area.
3
Analyze Setup 3, which compares a sodium chloride (NaCl\text{NaCl}) solution to deionized water.
This introduces solute concentration variations.
Solutes lower the chemical potential of the solvent and lower the vapor pressure, affecting evaporation independent of wind.
4
Analyze Setup 4, which measures evaporation over 60 minutes60\text{ minutes} versus 120 minutes120\text{ minutes}.
This setup varies the duration of the trial.
Unequal time intervals prevent a direct comparison of total volume lost unless normalized, representing differences in total duration of evaporation.

Key Concept

An experimental design must control all variables except the independent variable (wind speed). Any uncontrolled variable that can affect the dependent variable (evaporation rate) is a confounding factor that introduces potential error.
Estimated Time:2m 30s
Question 75Question

An investigator conducted two experiments to study the factors affecting the rate of a chemical reaction between zinc metal (Zn\text{Zn}) and hydrochloric acid (HCl\text{HCl}).

In Experiment 1, the investigator added 1.0 g1.0\text{ g} of zinc powder to 50 mL50\text{ mL} of 1.0 M1.0\text{ M} HCl\text{HCl} solution in a beaker. The reaction was carried out at different temperatures (20C20^\circ\text{C}, 30C30^\circ\text{C}, 40C40^\circ\text{C}, and 50C50^\circ\text{C}), and the time required for the zinc to completely dissolve was recorded for each trial.

In Experiment 2, the investigator added 1.0 g1.0\text{ g} of zinc powder to 50 mL50\text{ mL} of HCl\text{HCl} solution of different concentrations (0.5 M0.5\text{ M}, 1.0 M1.0\text{ M}, 1.5 M1.5\text{ M}, and 2.0 M2.0\text{ M}) in a beaker. The reaction was carried out at a constant temperature of 20C20^\circ\text{C}, and the time required for the zinc to completely dissolve was recorded for each trial.

Based on the descriptions of these experimental designs, is the statement that 'the temperature of the reaction was varied in Experiment 1 but was kept constant in Experiment 2' true or false?

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Answer: True

Answer

true
In Experiment 1, the investigator changed the temperature across trials (20C20^\circ\text{C}, 30C30^\circ\text{C}, 40C40^\circ\text{C}, and 50C50^\circ\text{C}), which means temperature was varied. In Experiment 2, the investigator maintained a constant temperature of 20C20^\circ\text{C} for all trials while varying the concentration of the acid. This directly confirms that temperature was varied in Experiment 1 and kept constant in Experiment 2, making the statement true.

Step-by-Step Solution

1
Analyze the role of temperature in Experiment 1.
The temperature was set to 20C20^\circ\text{C}, 30C30^\circ\text{C}, 40C40^\circ\text{C}, and 50C50^\circ\text{C} across different trials, which means it was varied.
To identify if temperature was an independent variable or a constant in the first experimental design.
2
Analyze the role of temperature in Experiment 2.
The temperature was kept at 20C20^\circ\text{C} for all trials, which means it was kept constant.
To identify if temperature was an independent variable or a constant in the second experimental design.
3
Evaluate the statement using the findings from Steps 1 and 2.
The statement claims temperature was varied in Experiment 1 and kept constant in Experiment 2. Since this matches our analysis, the statement is true.
To determine the final truth value of the target statement.

Key Concept

Distinguishing between independent variables and controlled constants across multiple experimental setups.
Estimated Time:45s
Question 76Question

A student proposed the following hypothesis regarding electrical circuits:

*Hypothesis*: As the cross-sectional area of a metal wire increases, its electrical resistance will increase because a larger wire contains more atoms that collide with and resist the flow of electrons.

To test this hypothesis, the student measured the electrical resistance of four copper wires, each 10 m10\text{ m} long but with different diameters, at a constant temperature of 20C20^\circ\text{C}. The results are shown in the table below:

WireDiameter (mm\text{mm})Cross-sectional area (mm2\text{mm}^2)Resistance (Ω\Omega)
10.50.204.00
21.00.791.00
31.51.770.44
42.03.140.25

Based on these results, how should the student modify the hypothesis?

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Answer: The student should modify the hypothesis to state that as the cross-sectional area of a wire increases, its electrical resistance decreases.

Answer

The student should modify the hypothesis to state that as the cross-sectional area of a wire increases, its electrical resistance decreases.
The correct answer states that the hypothesis should be modified to show that as the cross-sectional area of a wire increases, its electrical resistance decreases. The table shows that as the cross-sectional area increases from 0.20 mm20.20\text{ mm}^2 to 3.14 mm23.14\text{ mm}^2, the resistance decreases from 4.00 Ω4.00\ \Omega to 0.25 Ω0.25\ \Omega. Since the initial hypothesis predicted that resistance would increase as cross-sectional area increases, the experimental results contradict the hypothesis. Therefore, the hypothesis must be modified to reflect this inverse relationship.

Step-by-Step Solution

1
Analyze the student's initial hypothesis.
The initial hypothesis states that larger cross-sectional area leads to higher resistance (a direct relationship).
To evaluate the hypothesis, we must first define the expected relationship between the variables.
2
Examine the experimental data in the table to determine the actual relationship between cross-sectional area and resistance.
As the cross-sectional area increases from 0.20 mm20.20\text{ mm}^2 to 3.14 mm23.14\text{ mm}^2, the resistance decreases from 4.00 Ω4.00\ \Omega to 0.25 Ω0.25\ \Omega.
Comparing the independent variable (cross-sectional area) with the dependent variable (resistance) reveals the empirical trend.
3
Compare the empirical trend with the initial hypothesis and select the correct modification.
The empirical trend is inverse (area increases, resistance decreases), which contradicts the hypothesized direct relationship. Therefore, the hypothesis must be modified to state that resistance decreases as cross-sectional area increases.
A scientific hypothesis must be modified when experimental evidence consistently contradicts its predictions.

Key Concept

Evaluating and modifying a hypothesis based on conflicting experimental data.
Estimated Time:1m 30s
Question 77Question

To study thermal expansion in solids, a researcher proposed that the coefficient of linear expansion (α\alpha) of a metal rod depends on its starting length. Specifically, the researcher hypothesized that longer rods of the same metal would exhibit a larger value of α\alpha when subjected to the same temperature change.

To test this hypothesis, the researcher measured the physical expansion of three copper rods under identical heating conditions. The results of the measurements and the calculated values of α\alpha are recorded in the table below.

Copper RodInitial Length (L0L_0, m\text{m})Temperature Increase (ΔT\Delta T, C^\circ\text{C})Expansion (ΔL\Delta L, mm\text{mm})Coefficient of Linear Expansion (α\alpha, 106 C110^{-6}\text{ }^\circ\text{C}^{-1})
Rod A1.0500.8517
Rod B2.0501.7017
Rod C3.0502.5517

Based on the results of the experiment, does the data support the researcher's hypothesis, and how should the hypothesis be modified?

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Answer: No; the data show that the coefficient of linear expansion remains constant at 17×106 C117 \times 10^{-6}\text{ }^\circ\text{C}^{-1} regardless of the rod's initial length.

Answer

The experimental data does not support the hypothesis because the coefficient of linear expansion remains constant at 17×106 C117 \times 10^{-6}\text{ }^\circ\text{C}^{-1} for all initial lengths, meaning the hypothesis should be modified to state that the coefficient of linear expansion is independent of the initial length of the rod.
The correct option accurately states that the hypothesis is not supported because the coefficient of linear expansion (α\alpha) remains constant at 17×106 C117 \times 10^{-6}\text{ }^\circ\text{C}^{-1} for all three rods, regardless of their initial length. A scientific hypothesis must be rejected or modified when the measured property does not change in the predicted direction.

Step-by-Step Solution

1
Identify the core assertion of the researcher's hypothesis.
The hypothesis predicts that as the initial length (L0L_0) of a metal rod increases, the coefficient of linear expansion (α\alpha) of that metal will also increase.
Understanding the hypothesis defines the independent variable (initial length) and the dependent variable (coefficient of linear expansion) that must be compared using the data.
2
Analyze the data table to observe how the coefficient of linear expansion (α\alpha) behaves as the initial length increases.
As the initial length increases from 1.0 m1.0\text{ m} to 2.0 m2.0\text{ m} and then 3.0 m3.0\text{ m}, the calculated coefficient of linear expansion (α\alpha) remains constant at 17×106 C117 \times 10^{-6}\text{ }^\circ\text{C}^{-1}.
Evaluating the trend of the target variable (α\alpha) against the independent variable (L0L_0) determines whether the hypothesis is supported or refuted.
3
Determine the proper modification of the hypothesis based on the constant values of α\alpha.
Since α\alpha did not increase, the hypothesis is refuted. The modified hypothesis must reflect that the coefficient of linear expansion remains constant and is independent of the initial length of the rod.
Comparing the empirical data directly to the proposed hypothesis allows the researcher to correctly modify it to align with the experimental results.

Key Concept

Formulating and Modifying Hypotheses
Estimated Time:1m 15s
Question 78Question

Students conducted two experiments to study the growth of *Arabidopsis thaliana* plants over a 30-day period.

Experiment 1
Five groups of 10 plants were grown in identical pots containing the same soil type. Each group received a different concentration of Fertilizer X (0%, 1%, 2%, 3%, or 4% by volume) dissolved in water. All plants were kept under continuous white light at a constant temperature of 22°C and watered daily with 50 mL of their respective solution. The average height of the plants in each group was measured at the end of 30 days.

Experiment 2
Five groups of 10 plants were grown under the same conditions as in Experiment 1, except that all plants received a 2% solution of Fertilizer X, and each group was exposed to a different color of light (blue, green, red, yellow, or white).

Based on the descriptions of the two experiments, which of the following variables was kept constant in Experiment 1 but was varied in Experiment 2?

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Answer: The color of light the plants received

Answer

The color of light the plants received
The correct answer is the color of light the plants received. In Experiment 1, all plants were kept under continuous white light (a constant condition). In Experiment 2, the light color was the independent variable, meaning it was varied (blue, green, red, yellow, or white) across the different groups of plants.

Step-by-Step Solution

1
Identify the independent variable (what is varied) and the constants (what is kept the same) in Experiment 1.
In Experiment 1, the fertilizer concentration is varied (0% to 4%), while the light color (white light), soil type, temperature (22°C), watering volume (50 mL), and duration (30 days) are kept constant.
This establishes the control parameters and experimental variable for the first study.
2
Identify the independent variable and the constants in Experiment 2.
In Experiment 2, the light color is varied (blue, green, red, yellow, white), while the fertilizer concentration (2%), soil type, temperature, watering volume, and duration are kept constant.
This establishes the control parameters and experimental variable for the second study.
3
Compare the two sets of variables to find which condition is constant in Experiment 1 but varied in Experiment 2.
Light color is constant in Experiment 1 (white light) but varied in Experiment 2 (different colors).
This directly answers the comparative question asked in the stem.

Key Concept

Comparing and Contrasting Multiple Experimental Designs
Estimated Time:45s
Question 79Question

Suppose a student wants to modify an experiment measuring the evaporation rate of salt water (200 mL200\text{ mL} of 5%5\% saline solution heated by a 100 W100\text{ W} heat lamp placed 30 cm30\text{ cm} above the beaker in a draft-free room) to determine the specific impact of wind speed on the evaporation rate, while ensuring that the thermal energy input and other variables remain controlled. Arrange the following steps in the correct chronological sequence to successfully conduct this follow-up experiment.

Drag items to arrange them in the correct order

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Answer

The correct chronological sequence is: first, prepare the three identical saline solution beakers; second, position the heat lamp and the variable-speed fan at fixed distances relative to the beaker; third, select the wind speed setting and start the fan and lamp; and fourth, record the mass of the beaker at ten-minute intervals over one hour.
The correct sequence begins with preparing the identical solutions to establish controlled initial parameters. Next, the physical apparatus must be positioned to control the heat lamp distance and fan distance. Then, the specific wind speed is chosen and the trial is started by turning on the equipment. Finally, the mass is measured at regular intervals to track the evaporation rate.

Step-by-Step Solution

1
Prepare identical samples to control initial conditions.
Three beakers with equal volume (200 mL200\text{ mL}) and concentration (5%5\%) of saline solution.
Ensures that differences in evaporation are due only to the wind speed, not variations in initial volume or salinity.
2
Set up the physical apparatus with controlled physical dimensions.
The beaker, heat lamp (30 cm30\text{ cm} away), and fan (50 cm50\text{ cm} away) are positioned in a stable, repeatable configuration.
Ensures the heat energy delivered to the solution is constant across all trials, and the fan's physical distance does not vary.
3
Apply the independent variable (wind speed) and start the experimental conditions.
The trial begins under a specific, constant wind speed with simultaneous heating.
Allows the evaporation process to begin under the selected test condition.
4
Measure and record the dependent variable over the specified duration.
Mass data at 1010, 2020, 3030, 4040, 5050, and 6060 minutes.
Provides the raw data necessary to calculate the rate of mass loss (evaporation rate) over time for that specific wind speed.

Key Concept

Designing a controlled follow-up experiment requires isolating the new independent variable (wind speed) by maintaining all original variables (lamp distance, initial salinity, and volume) constant, and sequencing the steps from sample preparation to final measurement.
Question 80Question

A scientist conducted two experiments to study soil respiration (measured as the rate of carbon dioxide release, RsR_s, in g CO2/m2/day\text{g CO}_2/\text{m}^2/\text{day}) from a forest soil sample under different conditions.

ExperimentSoil Temperature (C^\circ\text{C})Soil Moisture Content (SMC)Observed Trend in RsR_s
120C20^\circ\text{C} (constant)Varied (10%10\%, 20%20\%, 30%30\%)RsR_s increases as SMC increases
2Varied (15C15^\circ\text{C}, 25C25^\circ\text{C}, 35C35^\circ\text{C})20%20\% (constant)RsR_s increases as temperature increases

Suppose a scientist wants to determine if the positive relationship between SMC and RsR_s observed at 20C20^\circ\text{C} remains positive at a near-freezing temperature of 2C2^\circ\text{C}. Which of the following modifications to the experimental design would best allow the scientist to test this hypothesis?

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Answer: Measure RsR_s of soil samples at a constant temperature of 2C2^\circ\text{C} while varying the SMC at 10%10\%, 20%20\%, and 30%30\%.

Answer

Measure RsR_s of soil samples at a constant temperature of 2C2^\circ\text{C} while varying the SMC at 10%10\%, 20%20\%, and 30%30\%.
To determine if the positive relationship between soil moisture content (SMC) and soil respiration rate (RsR_s) is preserved at a new constant temperature (2C2^\circ\text{C}), the scientist must isolate SMC as the independent variable. This is accomplished by holding the temperature constant at 2C2^\circ\text{C} and measuring RsR_s across the same range of SMC values (10%10\%, 20%20\%, and 30%30\%) used in the original experiment.

Step-by-Step Solution

1
Identify the goal of the proposed follow-up experiment.
The goal is to determine if the positive relationship between SMC and RsR_s holds at 2C2^\circ\text{C}.
Understanding the hypothesis is necessary to determine which variables must be manipulated and measured.
2
Identify the independent and dependent variables required to test the hypothesis.
The independent variable must be SMC (varied at 10%10\%, 20%20\%, and 30%30\%) and the dependent variable must be RsR_s (soil respiration rate).
To see if the relationship between moisture and respiration is altered, moisture must be varied while measuring respiration.
3
Identify the necessary control variables.
The temperature must be held constant at the new temperature of interest (2C2^\circ\text{C}).
If temperature is not held constant at 2C2^\circ\text{C}, the effect of temperature will confound the results.
4
Select the option that matches these design criteria.
Varying SMC while maintaining a constant temperature of 2C2^\circ\text{C} and measuring RsR_s is the correct experimental design.
This setup isolates the effect of SMC at the specific temperature of 2C2^\circ\text{C} without introducing confounding variables.

Key Concept

To test the relationship between an independent variable and a dependent variable under a new constant condition, the independent variable must be varied while keeping all other conditions constant.
Estimated Time:2m 0s
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